Optimizing of Cathode Interface Layers in Organic Solar Cells Using Polyphenols: An Effective Approach

The cathode interface layers (CILs) play a crucial role in enhancing the performance of organic solar cells (OSCs). However, challenges arise due to the high work function of CIL and inadequate contact with the active layer, leading to high interface trap recombination and poor charge extraction. In this study, a novel approach is proposed to improve charge injection and extraction in CILs by incorporating polyphenols, trihydroxybenzoic acid (TBA). Focusing on the CIL PDINN, its work function is successfully reduced from 4.14 eV to 3.80 eV and obtained charge collection efficiency of 91.23% through TBA regulation. These enhancements can be ascribed to improved contact between the active layer and the CILs, and enhanced the formation of a fine fiber phase width and inhibited interface recombination. As a result, the power conversion efficiency (PCE) of the binary OSCs comprising PM6: BTP-ec9 exhibits an increase from 18.2% to 19.3%, placing it among the one of the highest PCE values. Moreover, this approach demonstrated notable applicability for another CILs, as well as various OSCs systems. Overall, this research underscores the importance of regulating and modifying CILs to fully exploit their potential in OSCs devices, while laying the groundwork for optimizing their efficiency and stability. An induced regulation strategy for the cathode interface layers (CILs) in OSCs results in enhanced interaction between the CILs and active layer, augmenting the chemical adsorption between CIL and the Ag electrode, promoting more interface dipoles, effectively reducing the work function and trap-assisted recombination at the interface, and ultimately leading to improved PCE and OSCs stability. image