Self-assembled viologens on HOPG: solid-state NMR and AFM unravel the location of the anions

被引：0

作者：

Joseph, Jean ^{[1
]}

Raya, Jesus ^{[1
]}

Palmino, Frank ^{[2
]}

Jeannoutot, Judicael ^{[2
]}

Berville, Mathilde ^{[1
]}

Weiss, Jean ^{[1
]}

Cherioux, Frederic ^{[2
]}

Wytko, Jennifer A. ^{[1
]}

机构：

[1] Univ Strasbourg, Inst Chim, CNRS, UMR 7177, 4 Rue Blaise Pascal, F-67008 Strasbourg, France

[2] Univ Franche Comte, CNRS, FEMTO ST, F-25000 Besancon, France

来源：

NANOSCALE | 2024年 / 16卷 / 27期

关键词：

All Open Access; Hybrid Gold;

D O I：

10.1039/d4nr00894d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The controlled growth of self-assembled networks on surfaces based on viologen salts is a major scientific challenge due to their unique electronic properties. The combination of solid-state NMR spectroscopy and atomic force microscopy at ambient conditions can unravel the fine organization of the supramolecular network on a graphitic surface by positioning the counter-ions relative to the viologen cation. Complete organization of a network of viologens and PF6- anions on HOPG is unraveled by combining solid-state NMR and AFM.

引用

页码：13089 / 13095

页数：7

共 25 条

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