Solvent engineering enables longterm continuous lithium-mediated ammonia synthesis

被引：3

作者：

Sun, Ying ^{[1
,2
]}

Ma, Tianyi ^{[3
]}

Wang, Haihui ^{[4
]}

Qiu, Jieshan ^{[2
]}

机构：

[1] Liaoning Univ, Inst Clean Energy Chem, Coll Chem, Key Lab Green Synth & Preparat Chem Adv Mat Liaoni, Shenyang 110036, Peoples R China

[2] Beijing Univ Chem Technol, Coll Chem Engn, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

[3] RMIT Univ, Sch Sci, Melbourne, Vic 3000, Australia

[4] Tsinghua Univ, Dept Chem Engn, Beijing Key Lab Membrane Mat Beijing Key Lab & Eng, Beijing 100084, Peoples R China

来源：

CHEM | 2024年 / 10卷 / 06期

基金：

中国国家自然科学基金;

关键词：

REDUCTION;

D O I：

10.1016/j.chempr.2024.04.015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium-mediated nitrogen electroreduction (Li-NRR) is promising to replace the traditional Haber-Bosch strategy. Recently, the Chorkendorff group has realized a record-high 300 h of continuous LiNRR with high current-to-ammonia efficiency of X 64% in chain ether-based electrolyte. This solvent engineering strategy is a remarkable step for developing an efficient and durable Li-NRR process.

引用

页码：1641 / 1643

页数：3

共 10 条

[1] A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements [J].

Andersen, Suzanne Z. ;

Colic, Viktor ;

Yang, Sungeun ;

Schwalbe, Jay A. ;

Nielander, Adam C. ;

McEnaney, Joshua M. ;

Enemark-Rasmussen, Kasper ;

Baker, Jon G. ;

Singh, Aayush R. ;

Rohr, Brian A. ;

Statt, Michael J. ;

Blair, Sarah J. ;

Mezzavilla, Stefano ;

Kibsgaard, Jakob ;

Vesborg, Peter C. K. ;

Cargnello, Matteo ;

Bent, Stacey F. ;

Jaramillo, Thomas F. ;

Stephens, Ifan E. L. ;

Norskov, Jens K. ;

Chorkendorff, Ib .

NATURE, 2019, 570 (7762) :504-+

[2] Lithium-mediated nitrogen reduction to ammonia via the catalytic solid-electrolyte interphase [J].

Chang, Wesley ;

Jain, Anukta ;

Rezaie, Fateme ;

Manthiram, Karthish .

NATURE CATALYSIS, 2024, 7 (03) :231-241

[3] Enhancing Green Ammonia Electrosynthesis Through Tuning Sn Vacancies in Sn-Based MXene/MAX Hybrids [J].

Dai, Xinyu ;

Du, Zhen-Yi ;

Sun, Ying ;

Chen, Ping ;

Duan, Xiaoguang ;

Zhang, Junjun ;

Li, Hui ;

Fu, Yang ;

Jia, Baohua ;

Zhang, Lei ;

Fang, Wenhui ;

Qiu, Jieshan ;

Ma, Tianyi .

NANO-MICRO LETTERS, 2024, 16 (01)

[4] Hydrogen Radical-Induced Electrocatalytic N2 Reduction at a Low Potential [J].

Feng, Xueting ;

Liu, Jiyuan ;

Chen, Long ;

Kong, Ya ;

Zhang, Zedong ;

Zhang, Zixuan ;

Wang, Dingsheng ;

Liu, Wen ;

Li, Shuzhou ;

Tong, Lianming ;

Zhang, Jin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (18) :10259-10267

[5]

Fichter Fr., 1930, Helvetica Chimica Acta, V13, P1228, DOI [DOI 10.1002/HLCA.19300130604, 10.1002/hlca.19300130604]

[6] Continuous-flow electrosynthesis of ammonia by nitrogen reduction and hydrogen oxidation [J].

Fu, Xianbiao ;

Pedersen, Jakob B. ;

Zhou, Yuanyuan ;

Saccoccio, Mattia ;

Li, Shaofeng ;

Salinas, Rokas ;

Li, Katja ;

Andersen, Suzanne Z. ;

Xu, Aoni ;

Deissler, Niklas H. ;

Mygind, Jon Bjarke Valbaek ;

Wei, Chao ;

Kibsgaard, Jakob ;

Vesborg, Peter C. K. ;

Norskov, Jens K. ;

Chorkendorff, Ib .

SCIENCE, 2023, 379 (6633) :707-712

[7] Long-term continuous ammonia electrosynthesis [J].

Li, Shaofeng ;

Zhou, Yuanyuan ;

Fu, Xianbiao ;

Pedersen, Jakob B. ;

Saccoccio, Mattia ;

Andersen, Suzanne Z. ;

Enemark-Rasmussen, Kasper ;

Kempen, Paul J. ;

Damsgaard, Christian Danvad ;

Xu, Aoni ;

Sazinas, Rokas ;

Mygind, Jon Bjarke Valbaek ;

Deissler, Niklas H. ;

Kibsgaard, Jakob ;

Vesborg, Peter C. K. ;

Norskov, Jens K. ;

Chorkendorff, Ib .

NATURE, 2024, 629 (8010) :92-97

[8] Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions [J].

Luo, Yaru ;

Chen, Gao-Feng ;

Ding, Li ;

Chen, Xinzhi ;

Ding, Liang-Xin ;

Wang, Haihui .

JOULE, 2019, 3 (01) :279-289

[9] NH3 Electrosynthesis from N2 Molecules: Progresses, Challenges, and Future Perspectives [J].

Ren, Yongwen ;

Li, Shaofeng ;

Yu, Chang ;

Zheng, Yihan ;

Wang, Cheng ;

Qian, Bingzhi ;

Wang, Linshan ;

Fang, Wenhui ;

Sun, Ying ;

Qiu, Jieshan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (10) :6409-6421

[10] EFFICIENT ELECTROCHEMICAL REDUCTION OF N2 TO NH3 CATALYZED BY LITHIUM [J].

TSUNETO, A ;

KUDO, A ;

SAKATA, T .

CHEMISTRY LETTERS, 1993, (05) :851-854

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