The rise of borophene

被引:15
|
作者
Kumar, Prashant [1 ]
Singh, Gurwinder [1 ]
Bahadur, Rohan [1 ]
Li, Zhixuan [1 ]
Zhang, Xiangwei [1 ]
Sathish, C. I. [1 ]
Benzigar, Mercy R. [1 ]
Tran, Thi Kim Anh [1 ]
Padmanabhan, Nisha T. [2 ]
Radhakrishnan, Sithara [2 ]
Janardhanan, Jith C. [2 ]
Biji, Christy Ann [2 ]
Mathews, Ann Jini [2 ]
John, Honey [2 ]
Tavakkoli, Ehsan [3 ]
Murugavel, Ramaswamy [4 ]
Roy, Soumyabrata [5 ,6 ]
Ajayan, Pulickel M. [5 ]
Vinu, Ajayan [1 ]
机构
[1] Univ Newcastle, Coll Engn Sci & Environm CESE, Global Innovat Ctr Adv Nanomat, Univ Dr, Callaghan, NSW 2308, Australia
[2] Cochin Univ Sci & Technol, Dept Polymer Sci & Rubber Technol, Kochi 682022, Kerala, India
[3] Univ Adelaide, Sch Agr Food & Wine, Glen Osmond, SA 5064, Australia
[4] Indian Inst Technol, Dept Chem, Mumbai 400076, India
[5] Rice Univ, Dept Mat Sci & Nanoengn, Houston, TX 77005 USA
[6] Indian Inst Technol Kanpur, Dept Sustainable Energy Engn, Kanpur 208016, Uttar Pradesh, India
关键词
Borophene; Energy storage; Sensing; Catalysis; Biomedical; MESOPOROUS CARBON NITRIDE; PROMISING ANODE MATERIAL; PHASE TERT-BUTYLATION; CO2; CAPTURE; FEW-LAYER; CATALYTIC-ACTIVITY; OXYGEN EVOLUTION; POROUS STRUCTURE; DIRAC FERMIONS; LI-ION;
D O I
10.1016/j.pmatsci.2024.101331
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Borophene stands out uniquely among Xenes with its metallic character, Dirac nature, exceptional electron mobility, thermal conductivity, and Young ' s moduli - surpassing graphene. Invented in 2015, various methods, including atomic layer deposition, molecular beam epitaxy, and chemical vapor deposition, have successfully been demonstrated to realize substrate -supported crystal growth. Top -down approaches like micromechanical, sonochemical, solvothermal and modified hummer ' s techniques have also been employed. Thanks to its high electronic mobility, borophene serves as an active material for ultrafast sensing of light, gases, molecules, and strain. Its metallic behaviour, electrochemical activity, and anti -corrosive nature make it ideal for applications in energy storage and catalysis. It has been proven effective as an electrocatalyst for HER, OER, water splitting, CO 2 reduction, and NH 3 reduction reactions. Beyond this, borophene has found utility in bioimaging, biosensing, and various biomedical applications. A special emphasis will be given on the borophene nanoarchitectonics i.e. doped borophene and borophene-based hybrids with other 2D materials and nanoparticles and the theoretical understanding of these emerging materials systems to gain more insights on their electronic structure and properties, aiming to manipulate borophene for tailored applications.
引用
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页数:52
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