Microstructure and mechanical properties of microwave sintered (MgCoNiCuZn)O high-entropy ceramics

被引：7

作者：

Song, Bozhen ^{[1
]}

Dong, Wenzhe ^{[1
]}

Guan, Li ^{[1
]}

Lou, Yuanzheng ^{[2
]}

Zhu, Yujie ^{[1
]}

Zhang, Jiaxin ^{[1
]}

Fan, Lei ^{[1
]}

Guo, Xiaoqin ^{[1
]}

Shao, Gang ^{[2
]}

Zhang, Rui ^{[1
]}

机构：

[1] Zhengzhou Univ Aeronaut, Sch Mat Sci & Engn, Henan Key Lab Aeronaut Mat & Applicat Technol, Zhengzhou 450046, Henan, Peoples R China

[2] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2024年 / 50卷 / 07期

基金：

中国国家自然科学基金;

关键词：

High-entropy ceramics; Single-phase; Microwave sintering; Microscopic morphology; Impedance matching; RARE-EARTH; MECHANOCHEMICAL SYNTHESIS; HYDROXYAPATITE CERAMICS; OXIDE; DENSIFICATION; STRENGTH; BEHAVIOR; ALUMINA; ALLOYS;

D O I：

10.1016/j.ceramint.2024.01.202

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The microstructure, reaction mechanism and mechanical properties of (MgCoNiCuZn)O high-entropy ceramics prepared by microwave sintering technology were studied. Single -phase (MgCoNiCuZn)O high-entropy ceramics can be prepared in about 1 h when the preforming pressure is 5 MPa and the temperature is higher than 900 degrees C. By analyzing the microscopic morphology and density, it can be known that the density gradually increases with the increase of temperature. When the temperature is higher than 1000 degrees C, the pores in the sample indicate the packing, agglomeration and segregation of Cu2+ atoms at the grain boundaries. When the mass of the raw material is 20 g, it exhibits a good impedance matching effect during microwave heating. The sintered (MgCoNiCuZn)O ceramic with a density of 92.87 %, a flexural strength of 290 +/- 20 MPa, an elastic modulus of 187.05 +/- 5 GPa, and a microhardness of about 7 GPa.

引用

页码：22232 / 22242

页数：11

共 58 条

[31] Solution combustion synthesis and magnetic property of rock-salt (Co0.2Cu0.2Mg0.2Ni0.2Zn0.2)O high-entropy oxide nanocrystalline powder [J].

Mao, Aiqin ;

Xiang, Hou-Zheng ;

Zhang, Zhan-Guo ;

Kuramoto, Koji ;

Yu, Haiyun ;

Ran, Songlin .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2019, 484 :245-252

[32] Giant Enhancement of Exchange Coupling in Entropy-Stabilized Oxide Heterostructures [J].

Meisenheimer, P. B. ;

Kratofil, T. J. ;

Heron, J. T. .

SCIENTIFIC REPORTS, 2017, 7

[33]

Murty BS, 2014, HIGH-ENTROPY ALLOYS, P1

[34] Charge compensation mechanisms in Li-substituted high-entropy oxides and influence on Li superionic conductivity [J].

Osenciat, Nicolas ;

Berardan, David ;

Dragoe, Diana ;

Leridon, Brigitte ;

Hole, Stephane ;

Meena, Arun K. ;

Franger, Sylvain ;

Dragoe, Nita .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2019, 102 (10) :6156-6162

[35] Charge compensation and electrostatic transferability in three entropy-stabilized oxides: Results from density functional theory calculations [J].

Rak, Zs. ;

Rost, C. M. ;

Lim, M. ;

Sarker, P. ;

Toher, C. ;

Curtarolo, S. ;

Maria, J. -P. ;

Brenner, D. W. .

JOURNAL OF APPLIED PHYSICS, 2016, 120 (09)

[36] Densification behaviour of nanocrystalline hydroxyapatite bloceramics [J].

Ramesh, S. ;

Tan, C. Y. ;

Bhaduri, S. B. ;

Teng, W. D. ;

Sopyan, I. .

JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2008, 206 (1-3) :221-230

[37] Local structure of the MgxNixCoxCuxZnxO(x=0.2) entropy-stabilized oxide: An EXAFS study [J].

Rost, Christina M. ;

Rak, Zsolt ;

Brenner, Donald W. ;

Maria, Jon-Paul .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2017, 100 (06) :2732-2738

[38] Entropy-stabilized oxides [J].

Rost, Christina M. ;

Sachet, Edward ;

Borman, Trent ;

Moballegh, Ali ;

Dickey, Elizabeth C. ;

Hou, Dong ;

Jones, Jacob L. ;

Curtarolo, Stefano ;

Maria, Jon-Paul .

NATURE COMMUNICATIONS, 2015, 6

[39] High entropy oxides for reversible energy storage [J].

Sarkar, Abhishek ;

Velasco, Leonardo ;

Wang, Di ;

Wang, Qingsong ;

Talasila, Gopichand ;

de Biasi, Lea ;

Kuebel, Christian ;

Brezesinski, Torsten ;

Bhattacharya, Subramshu S. ;

Hahn, Horst ;

Breitung, Ben .

NATURE COMMUNICATIONS, 2018, 9

[40] Rare earth and transition metal based entropy stabilised perovskite type oxides [J].

Sarkar, Abhishek ;

Djenadic, Ruzica ;

Wang, Di ;

Hein, Christina ;

Kautenburger, Ralf ;

Clemens, Oliver ;

Hahn, Horst .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2018, 38 (05) :2318-2327

← 1 2 3 4 5 6 →