Ligand-Dominated Activation of CO2 and CS2 by the Putative Nickel Phosphiniminato Intermediates

被引：2
作者：
Yao, Changguang [1 ,2 ]
Goncalves, Theo P. [3 ,4 ]
Wang, Xiufang [3 ,4 ]
Luo, Lun [5 ,6 ]
Huang, Kuo-Wei [3 ,4 ]
机构：
[1] Nanchang Univ, Sch Chem & Chem Engn, Nanchang 330031, Peoples R China
[2] Nanchang Univ, Sch Resource & Environm, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Peoples R China
[3] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia
[4] King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
[5] Hubei Univ Med, Sch Pharmaceut Sci, Shiyan 442000, Peoples R China
[6] Hubei Univ Med, Hubei Key Lab Wudang Local Chinese Med Res, Shiyan 442000, Peoples R China
来源：
INORGANIC CHEMISTRY | 2024年 / 63卷 / 17期
基金：
中国国家自然科学基金;
关键词：
HYDROGEN BOND ACTIVATION; PINCER-TYPE LIGAND; N-ATOM TRANSFER; CARBON-DIOXIDE; DINITROGEN COMPLEX; IMIDO COMPLEX; AZIDO COMPLEX; REACTIVITY; METAL; NITRIDE;
D O I：
10.1021/acs.inorgchem.4c00429
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Room-temperature photoactivation of the first- and second-generation (PNP)-P-3-pincer nickel azido complexes 1a and 1b in the presence of CO2 or CS2 afforded N-bound carbamates, dithiocarbamates, and isothiocyanates, providing insights into CO2 and CS2 activation and demonstrating how a seemingly small difference in the ligand structure significantly influences the reactivity. Theoretical calculations disclosed that the charge of the phosphorus atom plays a critical role in determining the nitrogen atom transfer to form a plausible nickel phosphiniminato intermediate.
引用
收藏
页码：7820 / 7827
页数：8
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