Effect of Surface Oxidation and Crystal Thickness on the Magnetic Properties and Magnetic Domain Structures of Cr2Ge2Te6

被引:1
|
作者
Thomsen, Joachim Dahl [1 ,2 ]
Han, Myung-Geun [3 ]
Penn, Aubrey N. [4 ]
Foucher, Alexandre C. [2 ]
Geiwitz, Michael [5 ]
Burch, Kenneth Stephen [5 ]
Dekanovsky, Lukas [6 ]
Sofer, Zdenek [6 ]
Liu, Yu [3 ,7 ,8 ]
Petrovic, Cedomir [3 ,10 ]
Ross, Frances M. [2 ]
Zhu, Yimei [3 ]
Narang, Prineha [1 ,9 ]
机构
[1] Univ Calif Los Angeles, Coll Letters & Sci, Div Phys Sci, Los Angeles, CA 90095 USA
[2] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
[3] Condensed Matter Phys & Mat Sci Div, Brookhaven Natl Lab, Upton, NY 11973 USA
[4] MIT, MIT Nano, Cambridge, MA 02139 USA
[5] Boston Coll, Dept Phys, Chestnut Hill, MA 02467 USA
[6] Univ Chem & Technol Prague, Dept Inorgan Chem, Prague 6, Czech Republic
[7] Zhejiang Univ, Ctr Correlated Matter, Hangzhou 310058, Peoples R China
[8] Zhejiang Univ, Sch Phys, Hangzhou 310058, Peoples R China
[9] Univ Calif Los Angeles, Elect & Comp Engn Dept, Los Angeles, CA 90095 USA
[10] Shanghai Key Lab Mat Frontiers Res Extreme Environ, Shanghai Adv Res Phys Sci SHARPS, Shanghai 201203, Peoples R China
关键词
magnetism; two-dimensional materials; transmissionelectron microscopy; magnetic two-dimensional materials; Lorentz transmission electron microscopy; oxidation;
D O I
10.1021/acsnano.3c09858
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
van der Waals (vdW) magnetic materials, such as Cr2Ge2Te6 (CGT), show promise for memory and logic applications. This is due to their broadly tunable magnetic properties and the presence of topological magnetic features such as skyrmionic bubbles. A systematic study of thickness and oxidation effects on magnetic domain structures is important for designing devices and vdW heterostructures for practical applications. Here, we investigate thickness effects on magnetic properties, magnetic domains, and bubbles in oxidation-controlled CGT crystals. We find that CGT exposed to ambient conditions for 5 days forms an oxide layer approximately 5 nm thick. This oxidation leads to a significant increase in the oxidation state of the Cr ions, indicating a change in local magnetic properties. This is supported by real-space magnetic texture imaging through Lorentz transmission electron microscopy. By comparing the thickness-dependent saturation field of oxidized and pristine crystals, we find that oxidation leads to a nonmagnetic surface layer that is thicker than the oxide layer alone. We also find that the stripe domain width and skyrmionic bubble size are strongly affected by the crystal thickness in pristine crystals. These findings underscore the impact of thickness and surface oxidation on the properties of CGT, such as saturation field and domain/skyrmionic bubble size, and suggest a pathway for manipulating magnetic properties through a controlled oxidation process.
引用
收藏
页码:13458 / 13467
页数:10
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