Smart coating based on double stimuli-responsive microcapsules containing linseed oil and benzotriazole for active corrosion protection

被引：149
作者：
Leal, Debora Abrantes [1 ]
Riegel-Vidotti, Izabel Cristina [2 ]
Silva Ferreira, Mario Guerreiro [3 ]
Bruno Marino, Claudia Eliana [1 ]
机构：
[1] Univ Fed Parana, Mech Engn Dept, Curitiba, Parana, Brazil
[2] Univ Fed Parana, Chem Dept, Curitiba, Parana, Brazil
[3] Univ Aveiro, Aveiro Inst Mat, Mat Engn & Ceram Dept, Aveiro, Portugal
来源：
CORROSION SCIENCE | 2018年 / 130卷
关键词：
Carbon steel; Organic coatings; EIS; TEM; INHIBITOR; STEEL; MICRO;
D O I：
10.1016/j.corsci.2017.10.009
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Microcapsules containing linseed oil were synthesized by in situ polymerization method and benzotriazole was entrapped between polyelectrolytes layers assembled outside the microcapsules, using the Layer-by-Layer technique. The prepared microcapsules presented mean number diameter of 2.08 pm and released greater amount of benzotriazole in slightly acidic NaCI solution. The corrosion protection effect of the microcapsules was evaluated using a carbon steel substrate coated with an epoxy resin loaded with the microcapsules (4.8 wt %). Electrochemical impedance spectroscopy demonstrated the best performance of the loaded coating when compared to a control due to the stimuli-responsive release of linseed oil and benzotriazole.
引用
收藏
页码：56 / 63
页数：8
相关论文
共 26 条
  • [21] Improved active anticorrosion coatings using layer-by-layer assembled ZnO nanocontainers with benzotriazole
    Sonawane, S. H.
    Bhanvase, B. A.
    Jamali, A. A.
    Dubey, S. K.
    Kale, S. S.
    Pinjari, D. V.
    Kulkarni, R. D.
    Gogate, P. R.
    Pandit, A. B.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2012, 189 : 464 - 472
  • [22] Preparation and characterization of microcapsules containing linseed oil and its use in self-healing coatings
    Suryanarayana, C.
    Rao, K. Chowdoji
    Kumar, Dhirendra
    [J]. PROGRESS IN ORGANIC COATINGS, 2008, 63 (01) : 72 - 78
  • [23] Linseed oil-filled microcapsules containing drier and corrosion inhibitor - Their effects on self-healing capability of paints
    Szabo, Tamas
    Telegdi, Judit
    Nyikos, Lajos
    [J]. PROGRESS IN ORGANIC COATINGS, 2015, 84 : 136 - 142
  • [24] Autonomic healing of polymer composites
    White, SR
    Sottos, NR
    Geubelle, PH
    Moore, JS
    Kessler, MR
    Sriram, SR
    Brown, EN
    Viswanathan, S
    [J]. NATURE, 2001, 409 (6822) : 794 - 797
  • [25] "Smart" coatings for active corrosion protection based on multi-functional micro and nanocontainers
    Zheludkevich, M. L.
    Tedim, J.
    Ferreira, M. G. S.
    [J]. ELECTROCHIMICA ACTA, 2012, 82 : 314 - 323
  • [26] Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation
    Zhu, Dong Yu
    Rong, Min Zhi
    Zhang, Ming Qiu
    [J]. PROGRESS IN POLYMER SCIENCE, 2015, 49-50 : 175 - 220
123