The impact of Activation on the Performance of Optical Oxygen Sensing with the Luminescent Metal-Organic Framework MOF-76(Eu)

被引:1
作者
Kasper, Thomas [1 ]
Burkhart, Julian [1 ]
Mueller-Buschbaum, Klaus [1 ,2 ]
机构
[1] Justus Liebig Univ, Inst Inorgan & Analyt Chem, Heinrich Buff Ring 17, D-35392 Giessen, Germany
[2] Justus Liebig Univ, Ctr Mat Res LAMA, Heinrich Buff Ring 16, D-35392 Giessen, Germany
来源
CHEMPHOTOCHEM | 2024年 / 8卷 / 08期
关键词
oxygen sensing; metal-organic frameworks; luminescence; optical sensing; activation; COORDINATION POLYMERS; GAS SENSOR; BLUE; O-2; XRD;
D O I
10.1002/cptc.202300329
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of activation as key parameter for oxygen sensing by luminescent metal-organic frameworks has been investigated and quantified for the archetype MOF-76(Eu). Activation at different conditions (regarding temperature and solvent-exchange for distinct vacuum pressure and heating time), shows an influence on the overall quenching, response time and cyclability due to different pore accessibility and surface area and therefore on the overall performance of the sensor. The optical sensing process is based on luminescence quenching, analyzed from high vacuum (10-7 bar) to ambient pressure by dosing oxygen from 0.01 bar to 1 bar. Strong influence of the different activation parameters is observed, as MOF-76(Eu) activated at 50 degrees C shows limited quenching of the luminescence intensity within 30 min, while methanol-exchange and subsequent activation at 250 degrees C leads to a quenching rate of 98.6 %. In addition, the sensor response occurs more than 1000 times faster within 0.2 s. These results correlate well with physisorption data, which reveal a significant change in porosity and surface area according to the degree of activation. For a better understanding of the involved processes, adsorption isotherms were recorded, surface areas determined and correlated to the photophysical parameters, including Stern-Volmer kinetics and cycling experiments for the differently activated MOF sensors. Investigation on the influence of different activation parameters for the performance of MOF-76(Eu) for luminescent oxygen sensing showed that activation is essential to utilize the full potential of optical sensing regarding both, sensitivity by degree of quenching as well as response time of the sensor. image
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页数:12
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共 65 条
[41]   Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units [J].
Rosi, NL ;
Kim, J ;
Eddaoudi, M ;
Chen, BL ;
O'Keeffe, M ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (05) :1504-1518
[42]   Optical isotherms as a fundamental characterization method for gas sensing with luminescent MOFs by comparison of open and dense frameworks [J].
Schoenfeld, F. ;
Meyer, L. V. ;
Muehlbach, F. ;
Zottnick, S. H. ;
Mueller-Buschbaum, K. .
JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (10) :2588-2595
[43]   Air-Stable Solid-State Photoluminescence Standards for Quantitative Measurements Based on 4′-Phenyl-2,2′ : 6′,2′′-Terpyridine Complexes with Trivalent Lanthanides [J].
Sedykh, Alexander E. ;
Becker, Mariia ;
Seuffert, Marcel T. ;
Heuler, Dominik ;
Maxeiner, Moritz ;
Kurth, Dirk G. ;
Housecroft, Catherine E. ;
Constable, Edwin C. ;
Mueller-Buschbaum, Klaus .
CHEMPHOTOCHEM, 2023, 7 (02)
[44]   New highly porous aluminium based metal-organic frameworks: Al(OH)(ndc) (ndc=2,6-naphthalene dicarboxylate) and Al(OH)(bpdc) (bpdc=4,4′-biphenyl dicarboxylate) [J].
Senkovska, Irena ;
Hoffmann, Frank ;
Froeba, Michael ;
Getzschmann, Juergen ;
Boehlmann, Winfried ;
Kaskel, Stefan .
MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 122 (1-3) :93-98
[45]   Role of solvent-host interactions that lead to very large swelling of hybrid frameworks [J].
Serre, C. ;
Mellot-Draznieks, C. ;
Surble, S. ;
Audebrand, N. ;
Filinchuk, Y. ;
Ferey, G. .
SCIENCE, 2007, 315 (5820) :1828-1831
[46]   A LIFETIME-BASED OPTICAL CO2 GAS SENSOR WITH BLUE OR RED EXCITATION AND STOKES OR ANTI-STOKES DETECTION [J].
SIPIOR, J ;
BAMBOT, S ;
ROMAULD, M ;
CARTER, GM ;
LAKOWICZ, JR ;
RAO, G .
ANALYTICAL BIOCHEMISTRY, 1995, 227 (02) :309-318
[47]  
Stern O, 1919, PHYS Z, V20, P183
[48]   Tetraaquatrinitratoeuropium(III) dihydrate [J].
Stumpf, T ;
Bolte, M .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 :i10-I11
[49]   A highly fluorescent post-modified metal organic framework probe for selective, reversible and rapid carbon dioxide detection [J].
Tang, Yilong ;
Chen, Jinrning ;
Wu, Huafeng ;
Yu, Jinping ;
Jia, Jinlan ;
Xu, Wei ;
Fu, Yanyan ;
He, Qingguo ;
Cao, Huimin ;
Cheng, Jiangong .
DYES AND PIGMENTS, 2020, 172
[50]   The Kagome Topology of the Gallium and Indium Metal-Organic Framework Types with a MIL-68 Structure: Synthesis, XRD, Solid-State NMR Characterizations, and Hydrogen Adsorption [J].
Volkringer, Christophe ;
Meddouri, Mohamed ;
Loiseau, Thierry ;
Guillou, Nathalie ;
Marrot, Jerome ;
Ferey, Gerard ;
Haouas, Mohamed ;
Taulelle, Francis ;
Audebrand, Nathalie ;
Latroche, Michel .
INORGANIC CHEMISTRY, 2008, 47 (24) :11892-11901