Metal-Free ortho C-H Borylation of Thiobenzamides

被引：3
|
作者：
Lv, Jianxing [1 ,2 ]
Liang, Yixuan [1 ,2 ]
Ouyang, Yepeng [1 ,2 ]
Zhang, Hua [1 ,2 ]
机构：
[1] South Cent Minzu Univ, Sch Chem & Mat Sci, Key Lab Catalysis & Energy Mat Chem, Minist Educ, Wuhan 430074, Peoples R China
[2] South Cent Minzu Univ, Sch Chem & Mat Sci, Hubei Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 18期
基金：
中国国家自然科学基金;
关键词：
ALPHA-ARYLATION; HETEROAROMATIC-COMPOUNDS; BOND ARYLATION; THIOAMIDES; HYDROXYLATION;
D O I：
10.1021/acs.orglett.4c00691
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A BBr3-mediated S-directed ortho C-H borylation of thiobenzamides was developed. A variety of ortho-borylated thiobenzamides were obtained in moderate to good yields with a wide functional group tolerance under simple and metal-free conditions. This transformation provided a convenient and practical route to important functionalized thiobenzamides.
引用
收藏
页码：3709 / 3714
页数：6
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