Catalytic evaluation of Ni-3%Sr-/MCM-41 in dry and steam reforming of methane

被引:18
作者
Estalkhi, Motahareh Hasani [1 ]
Yousefpour, Mardali [1 ]
Koohestan, Hassan [1 ]
Taherian, Zahra [1 ,2 ]
机构
[1] Semnan Univ, Fac Mat & Met Engn, Semnan, Iran
[2] Univ Tabriz, Fac Chem, Dept Appl Chem, Res Lab Adv Water & Wastewater Treatment Proc, Tabriz, Iran
关键词
Dry reforming of methane; Steam refrming of methane; Ni catalyst; Strontium; Promoter; HYDROGEN-PRODUCTION; NI/SBA-15; CATALYSTS; SYNGAS PRODUCTION; NICKEL-CATALYSTS; PROMOTED NI; CO2; PERFORMANCE; SBA-15; MCM-41; CH4;
D O I
10.1016/j.ijhydene.2024.04.347
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A nickel catalyst on mesoporoussilica created through a direct synthesis and modified with a strontium promoter. After conducting dry and steam reforming tests, the prepared samples characterized using the XRD, XRF, BET, TPR and HR-TEM, and then considered to study the catalyst stability and activity. And, the CH 4 and CO 2 conversion and ratio of H 2 /CO with using the Sr - Ni/MCM-41 catalyst in the DRM and SRM processes at 700 degrees C, were determined about (73.3% and 80.6%), (55.81% and 60.25%), and (0.88 and 3.1), respectively. Furthermore, SEM, TPR, and TPD analysis were used to characterize the utilized catalyst. The finding demonstrated a good structural order and the specific surface area (SSA) of 889.5 m 2 /g. The presence of a strontium enhanced nickel oxide ' s reducibility and strengthened its interaction with the base. Furthermore, strontium enhanced the catalytic activity.
引用
收藏
页码:1344 / 1351
页数:8
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