Performance of CO 2-cured alkali-activated blast-furnace slag incorporating magnesium oxide

被引:4
作者
Jun, Yubin [1 ]
Han, Seong Ho [2 ]
Kim, Jae Hong [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Civil & Environm Engn, Daejeon 34141, South Korea
[2] Missouri Univ Sci & Technol, Civil Architectural & Environm Engn, Rolla, MO 65409 USA
基金
新加坡国家研究基金会;
关键词
CO2; curing; MgO; Calcite; Hydrotalcite; Carbonate ion; S-H; PHASE EVOLUTION; FLY-ASH; PART I; CARBONATION; HYDRATION; STRENGTH; MINERALIZATION; RESISTANCE; CHEMISTRY;
D O I
10.1016/j.conbuildmat.2024.136462
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
This study investigated characteristics of alkali -activated slags incorporating magnesium oxide (MgO) subjected to CO 2 curing. The samples were prepared by adding 2%, 5%, and 10% MgO to the total binder mass. The mixture was activated with potassium hydroxide (KOH) and cured in a CO 2 incubator for 3 days. The compressive strength of the MgO-incorporated CO 2 -cured alkali -activated slag was higher than that of the conventional alkali -activated slag at all ages up to 28 days. No reduction in the strength was observed over time. The enhanced strength was independent of MgO content. Combined X-ray diffraction with thermogravimetric analysis showed MgO accelerated the alkali activation by dissolving more Ca and Al ions from the slag. CO 2 curing supplied carbonate ions and produced calcium carbonate and hydrotalcite. The former aided in achieving a higher level of early age strength and gel pore refinement. Larger amount of the carbonates was formed under high MgO contents, which further enhanced the strength.
引用
收藏
页数:10
相关论文
共 55 条
  • [1] A review on alkali-activated slag concrete
    Amer, Ismail
    Kohail, Mohamed
    El-Feky, M. S.
    Rashad, Ahmed
    Khalaf, Mohamed A.
    [J]. AIN SHAMS ENGINEERING JOURNAL, 2021, 12 (02) : 1475 - 1499
  • [2] [Anonymous], 2014, Standard Practice for Mechanical Mixing of Hydraulic Cement Pastes and Mortars of Plastic Consistency, DOI [DOI 10.1520/C0305-14, 10.1520/C0305-14]
  • [3] Aydin S, 2012, ACI MATER J, V109, P463
  • [4] Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag - Part II: Effect of Al2O3
    Ben Haha, M.
    Lothenbach, B.
    Le Saout, G.
    Winnefeld, F.
    [J]. CEMENT AND CONCRETE RESEARCH, 2012, 42 (01) : 74 - 83
  • [5] Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag - Part I: Effect of MgO
    Ben Haha, M.
    Lothenbach, B.
    Le Saout, G.
    Winnefeld, F.
    [J]. CEMENT AND CONCRETE RESEARCH, 2011, 41 (09) : 955 - 963
  • [6] Influence of activator type on hydration kinetics, hydrate assemblage and microstructural development of alkali activated blast-furnace slags
    Ben Haha, M.
    Le Saout, G.
    Winnefeld, F.
    Lothenbach, B.
    [J]. CEMENT AND CONCRETE RESEARCH, 2011, 41 (03) : 301 - 310
  • [7] MgO content of slag controls phase evolution and structural changes induced by accelerated carbonation in alkali-activated binders
    Bernal, Susan A.
    Nicolas, Rackel San
    Myers, Rupert J.
    Mejia de Gutierrez, Ruby
    Puertas, Francisca
    van Deventer, Jannie S. J.
    Provis, John L.
    [J]. CEMENT AND CONCRETE RESEARCH, 2014, 57 : 33 - 43
  • [8] High-Resolution X-ray Diffraction and Fluorescence Microscopy Characterization of Alkali-Activated Slag-Metakaolin Binders
    Bernal, Susan A.
    Provis, John L.
    Rose, Volker
    Mejia de Gutierrez, Ruby
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (06) : 1951 - 1957
  • [9] The crystal structure of tobermorite 14 A (Plombierite), a C-S-H phase
    Bonaccorsi, E
    Merlino, S
    Kampf, AR
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (03) : 505 - 512
  • [10] Sodium silicate-based, alkali-activated slag mortars Part I. Strength, hydration and microstructure
    Brough, AR
    Atkinson, A
    [J]. CEMENT AND CONCRETE RESEARCH, 2002, 32 (06) : 865 - 879