Visible-light-driven synthesis of indoles via aerobic oxidative dehydrogenation at room temperature

被引：9

作者：

Wang, Zhidong ^{[1
]}

Fei, Guiqiang ^{[1
]}

Shi, Sanshan ^{[1
]}

Liu, Mengmeng ^{[1
]}

Li, Peng ^{[2
]}

Xie, Pan ^{[1
]}

机构：

[1] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Shaanxi Key Lab Chem Addit Ind, Xian 710021, Peoples R China

[2] Changqing Oilfield Co, Shale Oil Dev Branch, Qingcheng 745100, Peoples R China

来源：

MOLECULAR CATALYSIS | 2024年 / 564卷

关键词：

Photocatalysis; Oxidation; Dehydroaromatization; Indole; Nitrogen-containing; Heterocycles; METAL-FREE CATALYST; NITROGEN-HETEROCYCLES; N-HYDROXYPHTHALIMIDE; BENZYLIC ALCOHOLS; C-C; EFFICIENT; PHOTOREDOX; AROMATIZATION; COMPLEX; OXIDE;

D O I：

10.1016/j.mcat.2024.114334

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A photo-induced synthesis strategy has been developed to produce indole and other N-heterocycles via aerobic oxidative dehydrogenation. This process was performed under air at room temperature, resulting in moderate to good yields of indole, furan, quinoline and isoquinoline derivatives. Various sensitive functional groups are well tolerated in this reaction. This method is economical, highly efficient, and environmentally friendly, providing inspiration for the development of novel photochemical synthesis reactions.

引用

页数：8

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