A novel formulation representation regarding the equilibrium constant subject to reaction between N2 and O2

被引:2
|
作者
Wang, Jian-Feng [1 ]
Zhang, Hao [1 ]
Liang, Li-Xia [1 ]
Peng, Xiao-Long [2 ]
Wang, Chao-Wen [2 ]
Deng, Peng [2 ]
Ding, Qun-Chao [2 ]
Jia, Chun-Sheng [2 ,3 ]
机构
[1] SINOPEC, Northwest Oilfield Co, Urumqi 830011, Peoples R China
[2] Southwest Petr Univ, Natl Key Lab Oil & Gas Reservoir Geol & Exploitat, Chengdu 610500, Peoples R China
[3] Res Inst Tianfu New Energy, Chengdu 610041, Peoples R China
关键词
Nitrogen; Oxygen; Nitric oxide; Chemical reaction; Equilibrium constant; Formulation representation; GIBBS FREE-ENERGY; THERMODYNAMIC PROPERTIES; N-2; DECOMPOSITION; INJECTION; NITROGEN; OXYGEN; NO;
D O I
10.1016/j.comptc.2024.114758
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nitrogen (N2) and oxygen (O2) are the two main components in the air. Here, we report a novel formulation representation concerning the chemical equilibrium constant regarding the reaction of N2 and O2. It depends only on the standard experimental data subject to four molecular constants of N2, O2 and NO, while the conventional calculation schemes involve application of multiple experimental spectroscopic data or calorimetric data. Comparing two sets of experimentally measured data respecting the equilibrium constant with the theoretical prediction results obtained from the developed formulation and provided in the previous literature, we validate the reliability of the proposed prediction model. The mean absolute deviations between two experimental data sets and the predicted results from the proposed formulation are 2.983 % and 4.047 %, respectively, and the corresponding deviations of the same experimental measurements from the previous theoretical values reported in the literature are 11.07 % and 33.53 %, respectively.
引用
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页数:5
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