Cobalt catalyzed defunctionalization reactions

被引：1

作者：

Koracak, Ljiljana K. ^{[1
]}

Ajdacic, Vladimir D. ^{[1
]}

机构：

[1] Fac Chem Ltd, Innovat Ctr, Studentski Trg 12-16, Belgrade 11158, Serbia

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2024年 / 89卷 / 06期

关键词：

decarbonylation; decarboxylation; dehalogenation; desulfurization; deoxygenation; CARBOXYLIC-ACIDS; ARYL BROMIDES; REDUCTIVE CLEAVAGE; OXYGEN BONDS; DECARBONYLATION; DECHLORINATION; DEHALOGENATION; ALCOHOLS; HYDRODEHALOGENATION; HYDROGENOLYSIS;

D O I：

10.2298/JSC240315045K

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

: Catalytic defunctionalization of complex molecules has attracted significant attention in organic synthesis. This reaction enables common functional groups to serve as "traceless handles" for the new bond construction. In this mini-review, we have summarized the latest advances, methodologies and mechanistic insights into the selective cleavage of C-C and C-X bonds catalysed by cobalt complexes, shedding light on their increasing importance in modern chemical synthesis. The content of this review is categorized according to the type of functional group being removed from molecules.

引用

页码：785 / 806

页数：22

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