Nickel/Photoredox-Catalyzed Carbonylative Cross-Electrophile Coupling of Organohalides and Carboxylic Acid Esters with Phenyl Formate

被引：1

作者：

Yan, Xiao-Biao ^{[1
]}

Wang, Ning ^{[1
]}

Zhou, Jining ^{[1
]}

Ge, Haiyan ^{[1
]}

Wang, Zhicai ^{[1
]}

Lin, Yunzhi ^{[2
,3
]}

Shui, Hengfu ^{[1
]}

机构：

[1] Anhui Univ Technol, Sch Chem & Chem Engn, Anhui Key Lab Coal Clean Convers & High Valued Uti, Maanshan 243032, Peoples R China

[2] Westlake Univ, Dept Chem, Sch Sci, Hangzhou 310030, Peoples R China

[3] Westlake Univ, Res Ctr Ind Future, Hangzhou 310030, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 30期

关键词：

HALIDES; RADICALS; KETONES; ARYL;

D O I：

10.1021/acs.orglett.4c02502

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A photoinduced nickel-catalyzed reductive carbonylative coupling from organohalides and N-(acyloxy)phthalimide esters with phenyl formate as the carbonyl source has been developed. This reaction could perform smoothly under mild conditions, and a series of aryl-alkyl and alkyl-alkyl unsymmetrical ketones were produced without the need of stoichiometric metal reductants. Mechanistic studies indicate that this reaction was initiated from radical capture by Ni(I)-carbonyl species and subsequent rapid carbonyl insertion.

引用

页码：6518 / 6522

页数：5

共 48 条

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