An aluminum silicate fiber/alumina aerogel (ASF/AA) composite was prepared via the sol-gel method and atmospheric drying (APD) method using coal gangue (CG) solid waste from Xingxian county, Shanxi Province, as the aluminum source. Utilizing N-2 adsorption, scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and thermal conductivity meters, researchers examined the microstructure, composition, pore structure, and thermal insulation performance of ASF/AA composites. The thermal conductivity mechanism of the composite was analyzed. The experimental results show that most of the aluminum in CG is used. More importantly, in the process of aerogel synthesis, the atmospheric pressure drying method is used to obtain similar properties to supercritical drying. The composite material exhibits a low thermal conductivity of 0.047 W/(m<middle dot>K), a high specific surface area of 416 m(2)/g, and a low density of 0.26 g/cm(3) at room temperature. After heating at 1200 degrees C for 2 h, the thermal conductivity was as low as 0.071 W/(m<middle dot>K). This strategy can not only effectively achieve a reduction in the harmfulness of solid waste coal gangue, but also alleviate the shortage of related energy and resources in our country.