Flexible bifunctional wood-derived water filtration/photo-Fenton membrane for efficient purification of mixed organic wastewater

被引:1
作者
Fang, Haohang [1 ]
Yu, Qianqian [2 ]
Xie, Di [1 ]
Cai, Yiyan [1 ]
Sun, Jianping [1 ]
Chen, Boxi [1 ]
Huang, Houkai [1 ]
Li, Xin [2 ]
Dai, Siyang [2 ]
Shi, Shaohong [1 ]
Wu, Yiqiang [3 ]
Cheng, Fangchao [1 ,3 ]
机构
[1] Guangxi Univ, Sch Resources Environm & Mat, State Key Lab Featured Met Mat & Life cycle Safety, 100, Daxuedong Rd, Nanning 530004, Peoples R China
[2] Hechi Univ, Coll Chem & Bioengn, Guangxi Key Lab Sericulture Ecol & Appl Intelligen, Hechi 546300, Peoples R China
[3] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Peoples R China
基金
中国国家自然科学基金;
关键词
Photo-Fenton reaction; Degradation of mixed organic pollutants; Polymetallic oxide; Bifunctional catalytic system; Bionic design; PHOTO-FENTON; ULTRAFILTRATION MEMBRANES; HYBRID PHOTOCATALYST; PHENOLIC-COMPOUNDS; DEGRADATION; NANOPARTICLES; POLYSULFONE; FABRICATION; TIO2;
D O I
10.1016/j.colsurfa.2024.134498
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Membrane filtration technology demonstrates excellent continuous processing capability in organic wastewater treated processes, which is usually applied in continuous industrial processes. However, it still faces a contradiction between membrane flux and treatment efficiency. In this study, a flexible wood -based photocatalytic membrane with high membrane flux and exceptional photofenton performance was developed via partial fragment wood components and uniform loading of multi -metal oxide nanocatalysts, which breaks mentioned contradiction. The homogeneous and efficient wood -based dual -function water filtration/photofenton system was established by leveraging the directional porous structure of wood in conjunction with the nanocatalysts while adjusting their ratios, enabling effective purification of highly concentrated mixed organic wastewater. Under one solar intensity and negative pressure filtration (0.03 MPa), the system treated a mixed solution containing Rhodamine B, phenol, and tetracycline at a concentration of 280 mg L -1 with the removal efficiencies of 100 %, 93.4 %, and 90.2 %, respectively, and the membrane flux could up to 315.3 Lm -2 h -1 within one hour. The membrane showed a good recycling performance, and the decay rates were all below 5 % after five cycles. This wood -based dual -function water filtration/photo-Fenton system provides a new approach for the continuous dynamic treatment of high -concentration organic wastewater on an industrial scale.
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页数:11
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