An ultrahigh energy storage efficiency and recoverable density in Bi0.5Na0.5TiO3 with the modification of Sr0.85La0.1TiO3 via viscous polymer process

Currently, the development of dielectric ceramic capacitors is restricted by the contradiction between high efficiency and high recoverable density. Therefore, a novel strategy was designed to achieve a superior balance between them. Firstly, introducing Sr0.85La0.1TiO3 can enhance the content of the weak polar phase (P4bm) to become the main component, which can optimize the relaxor behaviour and improve efficiency. Then, the electric breakdown strength was effectively enhanced by grain refinement and viscous polymer processing. Finally, a high recoverable energy density of -5.3 J/cm3 and an excellent efficiency of -92.2% were attained in 0.9Bi0.5Na0.5TiO3-0.1Na0.8Sr0.1NbO3 ceramic with the addition of 0.35Sr0.85La0.1TiO3 after viscous polymer processing. The piezoelectric force microscope had been applied to prove the high activity of the polar nanoregions and finite element analysis was adopted to explain the reasons for the enhancing electric breakdown strength. In addition, this ceramic exhibits good temperature and frequency stability, and a fast discharging rate of 0.11 ms, making it a potential candidate for the actual application. (c) 2023 The Authors. Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).