Enhanced Low-Temperature Resistance of Lithium-Metal Rechargeable Batteries Based on Electrolyte Including Ethyl Acetate and LiDFOB Additives

To meet the demand for higher energy density in lithium-ion batteries and expand their application range, coupling lithium metal anodes with high-voltage cathodes is an ideal solution. However, the compatibility between lithium metal batteries and electrolytes affects their applicability. In this study, proposes a locally concentrated electrolyte based on ethyl acetate (EA) as the solvent, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) as the lithium salt, and lithium difluorooxoborate (LiDFOB) as a sacrificial agent to enhance the low-temperature and high-voltage endurance of Li//Lithium cobalt oxide (LCO) batteries. The Li//LCO battery can operate within the voltage range of 3 to 4.5 V, with an initial discharge specific capacity of 174.5 mAh g-1 at 20 degrees C. At -40 degrees C, after 200 cycles, the capacity retention rate is 87.7 %. It can operate under extreme conditions of -70 degrees C, with a discharge specific capacity of 112.6 mAh g-1. Additionally, LCO//HC batteries using this electrolyte demonstrate excellent performance. Present work provides a new perspective for the optimization of electrolytes for low-temperature lithium-ion batteries. Adjusting the solvent structure and reducing the desolvation energy enables the electrolyte to withstand high voltages and low temperatures. Li//LCO and HC//LCO batteries using this electrolyte can still operate within the voltage range of 3.0 to 4.5 V at -40 degrees C, exhibiting high discharge specific capacities and long cycling performance. image