Exploring Ferrocenyl Imine-Phosphane Complexes in Gold(I) Redox Switchable Catalysis and the Role of the "Magic Blue" Oxidant.

被引：0

作者：

Perez-Sanchez, J. C.

Herrera, R. P.

Gimeno, M. C.

机构：

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2024年 / 366卷 / 18期

关键词：

D O I：

10.1002/adsc.202400921

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Another class of gold(I) redox-switchable catalysts, incorporating ferrocenyl phosphane-imines, enriches the existing library of gold(I) complexes. Our catalyst proves efficacy in gold(I)-catalyzed cyclizations of furans and benzamides, exhibiting reversible "on-off" switching. Furthermore, we explored the unconventional role of "Magic Blue", commonly used as an oxidizing agent in various organic transformations, as a potential activator of the Au-Cl bond, initiating conventional gold(I) catalysis. image

引用

页码：3697 / 3697

页数：1