Recent advances in cobalt phosphide-based materials for electrocatalytic water splitting: From catalytic mechanism and synthesis method to optimization design

被引:53
作者
Deng, Rongrong [1 ]
Guo, Mengwei [1 ]
Wang, Chaowu [1 ]
Zhang, Qibo [1 ,2 ]
机构
[1] Kunming Univ Sci & Tech nol, Fac Met & Energy Engn, Key Lab Ion Liquids Met, 68 Wen Chang Rd,121 St, Kunming 650093, Peoples R China
[2] State Key Lab Complex Nonferrous Met Resources Cle, Kunming 650093, Peoples R China
基金
中国国家自然科学基金;
关键词
Co -P electrocatalysts; Water splitting; Hydrogen production; Catalytic mechanism; Synthesis technique; Optimization design; HYDROGEN-EVOLUTION-REACTION; EFFICIENT BIFUNCTIONAL ELECTROCATALYST; NANOSTRUCTURED NICKEL PHOSPHIDE; PH-UNIVERSAL ELECTROCATALYST; POROUS COP NANOSHEETS; DEEP EUTECTIC SOLVENT; OXYGEN EVOLUTION; DOPED COP; CARBON CLOTH; NANOWIRE ARRAYS;
D O I
10.1016/j.nanoms.2022.04.003
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Electrochemical water splitting has long been considered an effective energy conversion technology for transferring intermittent renewable electricity into hydrogen fuel, and the exploration of cost-effective and highperformance electrocatalysts is crucial in making electrolyzed water technology commercially viable. Cobalt phosphide (Co -P) has emerged as a catalyst of high potential owing to its high catalytic activity and durability in water splitting. This paper systematically reviews the latest advances in the development of Co -P -based materials for use in water splitting. The essential effects of P in enhancing the catalytic performance of the hydrogen evolution reaction and oxygen evolution reaction are first outlined. Then, versatile synthesis techniques for Co -P electrocatalysts are summarized, followed by advanced strategies to enhance the electrocatalytic performance of Co -P materials, including heteroatom doping, composite construction, integration with well -conductive substrates, and structure control from the viewpoint of experiment. Along with these optimization strategies, the understanding of the inherent mechanism of enhanced catalytic performance is also discussed. Finally, some existing challenges in the development of highly active and stable Co -P -based materials are clari fied, and prospective directions for prompting the wide commercialization of water electrolysis technology are proposed.
引用
收藏
页码:139 / 173
页数:35
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