Biomass-based production of trimellitic and trimesic acids

被引：0

作者：

Lin Yuan ^{[1
,2
]}

Yancheng Hu ^{[1
,3
]}

Guangyi Li ^{[1
]}

Fengan Han ^{[1
]}

Aiqin Wang ^{[1
]}

Yu Cong ^{[1
]}

Tao Zhang ^{[1
]}

Feng Wang ^{[4
]}

Ning Li ^{[1
]}

机构：

[1] CAS Key Laboratory of Science and Technology on Applied Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences

[2] University of Chinese Academy of Sciences, A Yuquan Road,Shijingshan District

[3] School of Chemical Engineering and Technology,China University of Mining and Technology

[4] State Key Laboratory of Catalysis,Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of

来源：

Green Energy & Environment | 2024年 / 9卷 / 08期

关键词：

D O I：

暂无

中图分类号：

TB383.2 []; TK6 [生物能及其利用];

学科分类号：

080703 ;

摘要：

The production of industrial chemicals with renewable biomass feedstock holds potential to aid the world in pursuing a carbon-neutral society.Trimellitic and trimesic acids are important commodity chemicals in industry that are prepared by the oxidation of petroleum-derived trimethylbenzene.To reduce the dependence on the limited oil source,we develop a potential sustainable alternative towards trimellitic and trimesic acids using biomass-based 2-methyl-2,4-pentandiol （MPD）,acrylate and crotonaldehyde as starting materials.The process for trimellitic acid includes dehydration/D-A reaction of MPD and acrylate,flow aromatization over Pd/C catalyst,hydrolysis and catalytic aerobic oxidation （60%overall yield）.The challenging regioselectivity issue of D-A reaction is tackled by a matched combination of temperature and deep eutectic solvent ChCl/HCO2H.Crotonaldehyde can also participate in the reaction,followed by Pd/C-catalyzed decarbonylation/dehydrogenation and oxidation to provide trimesic acid in 54%overall yield.Life cycle assessment implies that compared to conventional fossil process,our biomass-based routes present a potential in reducing carbon emissions.

引用

页码：1267 / 1278

页数：12

共 37 条

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