Synthesis, structure and properties of cyano-bridged hetero-bimetallic complex {[Cu(amet)2]2[Fe(CN)6]}∞

被引：1
|
作者：
孙献茹
王哲明
陈志达
卞江
严纯华
徐光宪
机构：
[1] State Key Laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemistry, Peking University,Beijing 100871, China
[2] State Key Laboratory of Structure Chemistry, Fujian Institute of Research onthe Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China ,State Key Laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemistry, Peking
来源：
ProgressinNaturalScience | 1999年 / 06期
基金：
中国国家自然科学基金;
关键词：
cyano-bridge; hetero-bimetallic complexes; molecular-based ferromagnet;
D O I：
暂无
中图分类号：
O614 [金属元素及其化合物];
学科分类号：
070301 ; 081704 ;
摘要：
A three-dimensional complex | [Cu(amet)2 ]2 [ Fe(CN)6] |∞(amet = NH2CH2CH2OH) has been synthesized and characterized by elemental analyses, IR, Mossbauer spectra and magnetic properties. X-ray diffraction analyses show that the complex belongs to the orthorhombic space group of Pnnm with α= 11 .649(2)A, b = 11.860(2) A, c = 7.944(2)A, V = 1097 .5(4) A3 , Z = 2. The three-dimensional complex consists of chain unit | [Cu(amet)2]2 [Fe(CN)6 ] | ∞ , in which each Fe is octahedrally coordinated and each Cu 2+ is, in the environment of triangular dipyramid.
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页码：26 / 32
页数：7
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