Investigation on performance of Eu:GO:KSrPO4 nanocomposite for MB dye photocatalytic degradation: Experimental and ANN modeling

被引：10
作者：
Athavale S. [1 ]
Barai D.P. [1 ]
Bhanvase B.A. [1 ]
Pandharipande S.L. [1 ]
机构：
[1] Department of Chemical Engineering, Laxminarayan Institute of Technology, Rashtrasant Tukadoji Maharaj Nagpur University, MS, Nagpur
来源：
Optik | 2023年 / 275卷
关键词：
ANN; Eu:GO/KSrPO[!sub]4[!/sub; MB dye; Phosphor; Sonochemical synthesis;
D O I：
10.1016/j.ijleo.2023.170561
中图分类号：
学科分类号：
摘要：
Ultrasonic-assisted synthesis of Eu-doped GO/KSrPO4 (Eu:GO/KSrPO4) nanocomposite has been accomplished in this work for its application for photocatalytic degradation of dye. Formation of the Eu:GO/KSrPO4 nanocomposite photocatalyst was confirmed through various characterization (SEM, UV/vis, and XRD) techniques. Additionally, experiments on photocatalytic degradation of methylene blue (MB) dye from wastewater allowed determination of photocatalytic activity of the produced nanocomposite material. Influence of different factors including Eu3+ ion concentration in KSrPO4:Eu3+ phosphor in the nanocomposite and other process parameters like catalyst dosage, amount of dye present in feed, pH, and synthesis technique was also assessed. A maximum percent removal of 82.75% of the dye was achieved for ultrasonically prepared Eu:GO/KSrPO4 photocatalyst with 0.5 mol.% Eu3+ ion doping at catalyst dose of 1 mg/ml, amount of dye present in feed of 20 ppm, and pH 10.56. ANN modeling was accomplished to predict the % methylene blue dye removal using prepared photocatalyst. © 2023 Elsevier GmbH
引用
收藏
相关论文
共 80 条
[31]  
Hassan M.S., Amna T., Yang O.-B., Kim H.-C., Khil M.-S., TiO2 nanofibers doped with rare earth elements and their photocatalytic activity, Ceram. Int., 38, pp. 5925-5930, (2012)
[32]  
Park B.-G., Photoluminescence of Eu3+-doped CaTiO3 perovskites and their photocatalytic properties with a metal ion loading, Chem. Phys. Lett., 722, pp. 44-49, (2019)
[33]  
Chen M., Xiong Q., Liu Z., Qiu K., Xiao X., Synthesis and photocatalytic activity of Na+ co-doped CaTiO3:Eu3+ photocatalysts for methylene blue degradation, Ceram. Int., 46, pp. 12111-12119, (2020)
[34]  
Gohr M.S., Hafez H., Saif M.M., Soliman H.M.A., Abdel-Mottaleb M.S.A., Facile hydrothermal synthesis of Sm and Eu doped TiO2/graphene oxide nanocomposites for photocatalytic applications, Egypt. J. Chem., 63, (2019)
[35]  
Shandilya P., Sudhaik A., Raizada P., Hosseini-Bandegharaei A., Singh P., Rahmani-Sani A., Thakur V., Saini A.K., Synthesis of Eu3+−doped ZnO/Bi2O3 heterojunction photocatalyst on graphene oxide sheets for visible light-assisted degradation of 2,4-dimethyl phenol and bacteria killing, Solid State Sci., 102, (2020)
[36]  
Naorem R.S., Singh N.P., Singh N.M., Photoluminescence studies of Ce3+ ion-doped BiPO4 phosphor and its photocatalytic activity, Int. J. Appl. Ceram. Technol., 17, pp. 2744-2751, (2020)
[37]  
Bajpai J.S., Barai D.P., Bhanvase B.A., Pawade V.B., Sonochemical preparation and characterization of Sm‐doped GO/KSrPO 4 nanocomposite photocatalyst for degradation of methylene blue dye, Water Environ. Res., 94, (2022)
[38]  
Ma X., Zhang J., Li H., Duan B., Guo L., Que M., Wang Y., Violet blue long-lasting phosphorescence properties of Mg-doped BaZrO 3 and its ability to assist photocatalysis, J. Alloy. Compd., 580, pp. 564-569, (2013)
[39]  
Eun S., Mavengere S., Kim J., Preparation of Ag-TiO2/Sr4Al14O25:Eu2+,Dy3+ photocatalyst on phosphor beads and its photoreaction characteristics, Catalysts, 11, (2021)
[40]  
Tang Y., Hu S., Lin C.C., Bagkar N.C., Liu R., pp. 88-91, (2012)
12345678