Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents

被引：0
|
作者：
Sakakibara Y. [1 ]
Itami K. [2 ]
Murakami K. [1 ]
机构：
[1] Department of Chemistry, Kwansei Gakuin University, Gakuen Uegahara 1, Sanda, Hyogo
[2] Institute of Transformative Bio─Molecules (WPI─ITbM) and Graduate School of Science, Nagoya University, Nagoya
来源：
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry | 2023年 / 81卷 / 11期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
D O I：
10.5059/yukigoseikyokaishi.81.1073
中图分类号：
学科分类号：
摘要：
Carboxylic acids are one of the most important functional groups found in various feedstocks. Their signi~cance lies in their pivotal role as key intermediates in selective transformations during organic synthesis. Despite the existence of various decarboxylative transformation reactions such as Kolbe dimerization, these methods still exhibit certain limitations that present opportunities for further improvement. In this account, we present our recent studies on the application of photocatalytic decarboxylative transformation that allows the divergent transformation of carboxylic acids. © 2023 Society of Synthetic Organic Chemistry. All rights reserved.
引用
收藏
页码：1050 / 1061
页数：11
相关论文
共 50 条
  • [1] Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents
    Sakakibara, Yota
    Itami, Kenichiro
    Murakami, Kei
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023, 81 (11) : 1050 - 1061
  • [2] Hypervalent Iodine(III)-Mediated Oxidative Decarboxylation of β,γ-Unsaturated Carboxylic Acids
    Kiyokawa, Kensuke
    Yahata, Shunsuke
    Kojima, Takumi
    Minakata, Satoshi
    ORGANIC LETTERS, 2014, 16 (17) : 4646 - 4649
  • [3] HYPERVALENT IODINE IODINATIVE DECARBOXYLATION OF CUBYL AND HOMOCUBYL CARBOXYLIC-ACIDS
    MORIARTY, RM
    KHOSROWSHAHI, JS
    DALECKI, TM
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (09) : 675 - 676
  • [4] HYPERVALENT IODINE IODINATIVE DECARBOXYLATION OF CUBYL AND HOMOCUBYL CARBOXYLIC-ACIDS
    MORIARTY, RM
    KHOSROWSHAHI, JS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 41 - ORGN
  • [5] Decarboxylative Alkynylation and Cyanation of Carboxylic Acids using Photoredox Catalysis and Hypervalent Iodine Reagents
    Le Vaillant, Franck
    Waser, Jerome
    CHIMIA, 2017, 71 (04) : 226 - 230
  • [6] A mild method for synthesizing carboxylic acids by oxidation of aldoximes using hypervalent iodine reagents
    Nakamura, Akira
    Kanou, Hodaka
    Tanaka, Junki
    Imamiya, Akira
    Maegawa, Tomohiro
    Miki, Yasuyoshi
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (04) : 541 - 544
  • [7] Hypervalent Iodine(III)-Mediated Oxidative Decarboxylation of β-Keto Acids
    Yuan, Zhipeng
    Zhao, Tiantian
    Yu, Tianyang
    Wang, Junru
    Wei, Hao
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 6 (03) : 262 - 264
  • [8] Photocatalytic decarboxylation of free carboxylic acids and their functionalization
    Mondal, Subal
    Mandal, Subham
    Mondal, Soumya
    Midya, Siba P.
    Ghosh, Pradyut
    CHEMICAL COMMUNICATIONS, 2024, 60 (72) : 9645 - 9658
  • [9] Reactivity of hypervalent iodine reagents with arylalkenoic acids.
    Boye, AC
    Wirth, T
    French, AN
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U284 - U284
  • [10] APPLICATION OF HYPERVALENT IODINE REAGENTS TO THE SYNTHESIS OF AMINOPHOSPHONIC ACIDS
    WASIELEWSKI, C
    TOPOLSKI, M
    DEMBROWSKI, L
    JOURNAL FUR PRAKTISCHE CHEMIE, 1989, 331 (03): : 507 - 510
12345