Porous hemispherical Au@PdAg catalysts for enhancing ethanol electrooxidation

Direct ethanol fuel cell can convert chemical energy into electric energy directly, and has the advantages of being free from Carnot cycle and being friendly to environment, so it has a broad application prospect. However, the insufficient activity and toxicity resistance of anodic catalysts limit their commercial application, mainly due to the limited adsorption sites and the toxic inactivation of catalysts resulting from the production of toxic intermediates (COads) during the ethanol oxidation reaction (EOR) process. In this study, the Au@PdAg porous hemispherical catalyst assembled by nanotubes was successfully prepared by soft template method and coreduction method using dioctadecyl dimethyl ammonium chloride (DODAC) as surfactant, and its EOR performance was tested. Au@Pd1.0Ag1.0 has the highest mass current density with a peak value of 4048.8 mA mg(-1) which is 7.8 times of Pd/C (JM). After 5000 s stability test, the residual current density value is still 863.4 mA mg(-) Pd . The results showed that the introduction of the oxygenophilic metal Ag was conducive to the formation of OHads and the oxidation of COads. The porous structure of the nanotube assembly facilitates electron transfer and provides more adsorption sites, which makes the catalyst show good electrocatalytic activity and anti-CO poisoning ability.