One-pot synthesis of g-C3N4/N-doped CeO2 nanocomposites and their potential visible light-driven photocatalytic degradation of methylene blue dye

被引:6
作者
Karthik, A. S. [1 ,2 ]
Agrawal, Smita [3 ]
Senthil, S. [1 ]
Debnath, Abhijit [4 ]
Devanesan, Sandhanasamy [5 ]
Zohier, Ahmed E. A. [6 ]
Vignesh, S. [7 ,8 ]
机构
[1] Govt Arts Coll A, Dept Chem, Salem 636007, Tamilnadu, India
[2] Arignar Anna Govt Arts Coll, Dept Chem, Attur 636121, Tamilnadu, India
[3] Rajmata Vijayaraje Scindia Krishi Vishwa Vidyalaya, Dept Hort, Gwalior 474002, Madhya Pradesh, India
[4] Krishi Vigyan Kendra, Dept Hort, New Delhi 799278, Tripura, India
[5] King Saud Univ, Dept Phys & Astron, Coll Sci, POB 2455, Riyadh 11451, Saudi Arabia
[6] King Saud Univ, Dept Sci Technol, POB 2454, Riyadh 11451, Saudi Arabia
[7] Saveetha Univ, Saveetha Inst Med & Tech Sci, Saveetha Sch Engn, Dept Appl Chem, Chennai 602105, Tamil Nadu, India
[8] Yeungnam Univ, Sch Chem Engn, 280 Daehak Ro, Gyeongbuk 38541, Gyeongsan, South Korea
关键词
g-C3N4/N-CeO2; NCs; Methylene blue dye; Photocatalytic degradation; Band gap; Solar light; CEO2/G-C3N4; COMPOSITES; GRAPHENE OXIDE; ENHANCEMENT; REMOVAL;
D O I
10.1007/s10653-024-02007-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the pursuit of efficient photocatalytic materials for environmental applications, a new series of g-C3N4/N-doped CeO2 nanocomposites (g-C3N4/N-CeO2 NCs) was synthesized using a straightforward dispersion method. These nanocomposites were systematically characterized to understand their structural, optical, and chemical properties. The photocatalytic performance of g-C3N4/N-CeO2 NCs was evaluated by investigating their ability to degrade methylene blue (MB) dye, a model organic pollutant. The results demonstrate that the integration of g-C3N4 with N-doped CeO2 NCs reduces the optical energy gap compared to pristine N-doped CeO2, leading to enhanced photocatalytic efficiency. It is benefited from the existence of g-C3N4/N-CeO2 NCs not only in promoting the charge separation and inhibits the fast charge recombination but also in improving photocatalytic oxidation performance. Hence, this study highlights the potential of g-C3N4/N-CeO2 NCs as promising candidates for various photocatalytic applications, contributing to the advancement of sustainable environmental remediation technologies.
引用
收藏
页数:15
相关论文
共 38 条
[21]   Development of biohybrid Ag2CrO4/rGO based nanocomposites with stable flotation properties as enhanced Photocatalyst for sewage treatment and antibiotic-conjugated for antibacterial evaluation [J].
Malathy, A. ;
Manikandan, V. ;
Devanesan, Sandhanasamy ;
Farhat, Karim ;
Priyadharsan, A. ;
Ragavendran, C. ;
Ragupathy, S. ;
Ranjith, R. ;
Sivakumar, S. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2023, 244
[22]   Carbon-based nanomaterial intervention and efficient removal of various contaminants from effluents - A review [J].
Manimegalai, Sengani ;
Vickram, Sundaram ;
Deena, Santhana Raj ;
Rohini, Karunakaran ;
Thanigaivel, Sundaram ;
Manikandan, S. ;
Subbaiya, R. ;
Karmegam, N. ;
Kim, Woong ;
Govarthanan, M. .
CHEMOSPHERE, 2023, 312
[23]   NiO/CuO/TiO2 TERNARY COMPOSITES: DEVELOPMENT, PHYSICOCHEMICAL CHARACTERIZATION AND PHOTOCATALYTIC DEGRADATION STUDY OVER REACTIVE ORANGE 30 SOLUTIONS UNDER SOLAR LIGHT IRRADIATION [J].
Muthamilarasu, A. ;
Sivakumar, S. ;
Divya, G. ;
Sivakumar, M. ;
Sakthi, D. .
ADVANCES IN MATERIALS SCIENCE, 2022, 22 (01) :36-54
[24]   Synthesis, characterization, kinetics and adsorption properties of Pt-Co@GO nano-adsorbent for methylene blue removal in the aquatic mediums using ultrasonic process systems [J].
Nas, Mehmet Salih ;
Calimli, Mehmet Harbi ;
Burhan, Hakan ;
Yilmaz, Mustafa ;
Mustafov, Sibel Demiroglu ;
Sen, Fatih .
JOURNAL OF MOLECULAR LIQUIDS, 2019, 296
[25]   Design and fabrication of g-C3N4/Bi2S3 heterojunction photocatalysts for efficient organic pollutant degradation and antibacterial activity [J].
Rajendran, Ranjith ;
Rojviroon, Orawan ;
Arumugam, Priyadharsan ;
Natchimuthu, Karmegam ;
Vasudevan, Vasanthakumar ;
Kannupaiyan, Jothimani ;
Muangmora, Rattana ;
Phouheuanghong, Phoutthideth ;
Rojviroon, Thammasak .
JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 976
[26]   Construction of novel g-C3N4 coupled efficient Bi2O3 nanoparticles for improved Z-scheme photocatalytic removal of environmental wastewater contaminant: Insight mechanism [J].
Ranjith, R. ;
Vignesh, S. ;
Balachandar, Ramalingam ;
Suganthi, S. ;
Raj, V. ;
Ramasundaram, Subramaniyan ;
Sundar, J. Kalyana ;
Shkir, Mohd ;
Oh, Tae Hwan .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2023, 330
[27]   Construction of g-C3N4/CdS/BiVO4 ternary nanocomposite with enhanced visible-light-driven photocatalytic activity toward methylene blue dye degradation in the aqueous phase [J].
Ranjith, R. ;
Karmegam, Natchimuthu ;
Alsawalha, Murad ;
Hu, Xuefeng ;
Jothimani, K. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2023, 330
[28]   Advanced technologies for the determination of quantitative structure-activity relationships and degradation efficiency of micropollutants and their removal in water - A review [J].
Ratchnashree, S. R. ;
Karmegam, N. ;
Selvam, Masilamani ;
Manikandan, S. ;
Deena, Santhana Raj ;
Subbaiya, R. ;
Vickram, A. S. ;
Kim, Woong ;
Govarthanan, M. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2023, 904
[29]   Controllable synthesis of CeO2/g-C3N4 composites and their applications in the environment [J].
She, Xiaojie ;
Xu, Hui ;
Wang, Hefei ;
Xia, Jiexiang ;
Song, Yanhua ;
Yan, Jia ;
Xu, Yuanguo ;
Zhang, Qi ;
Du, Daolin ;
Li, Huaming .
DALTON TRANSACTIONS, 2015, 44 (15) :7021-7031
[30]   Photocatalytic dye degradation and antibacterial activities of CeO2/g-C3N4 nanomaterials for environmental applications [J].
Shoran, Sachin ;
Chaudhary, Sudesh ;
Sharma, Anshu .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (44) :98682-98700