Hydrothermal synthesis of NiS2@SnS2 nanohybrid for the water splitting application

被引:40
作者
Abdullah, Muhammad [1 ]
Alyousef, Haifa A. [2 ]
Alotaibi, B. M. [2 ]
Alrowaily, Albandari. W. [2 ]
Al-Harbi, Nuha [3 ]
Henaish, A. M. A. [4 ,5 ]
Dahshan, A. [6 ]
机构
[1] Univ Lahore, Dept Chem, Govt Coll, Lahore 54000, Pakistan
[2] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, POB 84428, Riyadh 11671, Saudi Arabia
[3] Umm Al Qura Univ, Fac Appl Sci, Dept Phys, Mecca, Saudi Arabia
[4] Tanta Univ, Fac Sci, Phys Dept, Tanta 31527, Egypt
[5] Ural Fed Univ, NANOTECH Ctr, Ekaterinburg 620002, Russia
[6] King Khalid Univ, Coll Sci, Dept Phys, Abha 61413, Saudi Arabia
关键词
NiS2@SnS2; Hydrothermal method; Electrocatalyst; Tafel slope; HER; HYDROGEN; SNS2;
D O I
10.1016/j.matchemphys.2024.129361
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The potential capabilities of stannous sulphide (SS) in the domain of the hydrogen evolution process (HER) have attracted significant interest. By employing a straightforward single-step hydrothermal method, we successfully boosted the HER performance of SnS2. This was achieved by fabricating a nanocomposite consisting of nickel sulphide (NS) and tin sulphide (SS) nanostructure. The resulting NS@SS nanocomposite shows the superior electrocatalytic behavior for the HER compared to pristine NS and SS material. The composite exhibited a morphology with two distinct phases, such as nanoparticles and nanorod structures that are responsible for good electrochemical properties. The NS@SS nanocomposite has several advantages for enhancing HER electroactivity, including a greater active surface area, increased edge-terminated structures, and better conductivity. The catalyst has high stability in alkaline solutions and demonstrates a low overpotential (eta) of 155 mV@ 10 mA cm(-2) with a Tafel slope of 34 mV dec(-1). The current results show that the NS@SS nanocomposites are a potential candidate for the energy production materials and energy conversion system.
引用
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页数:8
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