Preparation of Fluorinated Acrylate Emulsion and Its Application to Fabric

被引：0
|
作者：
Zheng J. [1 ]
Li K. [1 ]
Huang C. [1 ]
Long Z. [1 ]
Zhang D. [1 ,2 ]
机构：
[1] Key Laboratory of Eco-Textiles, Ministry of Education, Jiangnan University, Wuxi
[2] State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai
来源：
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2019年 / 35卷 / 02期
关键词：
Emulsion polymerization; Infrared spectrum; Super-hydrophobicity; Tridecafluorooctyl acrylate;
D O I：
10.16865/j.cnki.1000-7555.2019.0035
中图分类号：
学科分类号：
摘要：
The ternary element emulsion polymerization method was used in this paper. Tridecafluorooctyl acrylate (PFOA) was selected as fluoromonomer and free-radical copolymerization was carried out in water with methyl methacrylate (MMA) and styrene (St) as auxiliary monomers to prepare fluorocopolymer (FP) emulsion. Based on the study of its structural properties and microstructure, the FP was finished on different fiber fabric substrates. The surface morphology of polymer was studied by infrared spectroscopy, contact angle and etc. The changes of static contact angle, water washing resistance and moisture permeability were investigated before and after finishing. The results show that the FP film is a polymer film with nanoscale size. The finished cotton, polyester, polyester/cotton, nylon and wool fabrics all have super-hydrophobic effects. After washing 30 times, the finished polyester, nylon and wool fabrics still show good hydrophobic effect, but the hydrophobic effects of cotton and polyester/cotton fabrics are not ideal. © 2019, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
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页码：29 / 35and40
页数：3511
相关论文
共 15 条
  • [1] Huang P.Y., Chao Y.C., Liao Y.T., Enhancement of the water repellency durability of the fabrics treated by fluorinated nanocopolymer emulsions, J. Appl. Polym. Sci., 104, pp. 2451-2457, (2007)
  • [2] Roach P., Shirtcliffe N.J., Newton M.I., Progress in superhydrophobic surface development, Soft Matter, 4, pp. 224-240, (2008)
  • [3] Zhang X.L., Liu S.F., Liu L.L., Progress of superhydrophobic fabric surface, Textile Auxiliaries, 27, 10, pp. 1-3, (2010)
  • [4] Muriel C., EC proposes laws to restrict PFOS, Eur. Chem. News, 83, (2005)
  • [5] Gao Y., Synthesis of fluorine- and silicon-containing hydrophobic and oleophobic polymers and their applications on cotton fabric, (2011)
  • [6] Zhang X., Shi F., Niu J., Et al., Superhydrophobic surfaces: from structural control to functional application, J. Mater. Chem., 18, pp. 621-633, (2008)
  • [7] Hayn R.A., Owens J.R., Boyer S.A., Et al., Preparation of highly hydrophobic and oleophobic textile surfaces using microwave-promoted silane coupling, J. Mater. Sci., 46, pp. 2503-2509, (2011)
  • [8] Lee K., Hwang J., Ahn Y., Fabrication of superhydrophobic surface on a cellulose-based material via chemical modification, Bull. Korean Chem. Soc., 35, pp. 1545-1548, (2014)
  • [9] Shang Q., Zhou Y., Xiao G., A simple method for the fabrication of silica-based superhydrophobic surfaces, J. Coat. Technol. Res., 11, pp. 509-515, (2014)
  • [10] Xu W., Synthesis, characterization and application of fluorine-containing polyacrylate soap-free latexes, (2013)
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