Unraveling many-body effects in ZnO: Combined study using momentum-resolved electron energy-loss spectroscopy and first-principles calculations

We present a detailed study of the dielectric response of ZnO using a combination of low -loss momentumresolved electron energy -loss spectroscopy (EELS) and first -principles calculations at several levels of theory, from the independent particle and the random phase approximation with different variants of density functional theory (DFT), including hybrid and DFT + U schemes; to the Bethe-Salpeter equation (BSE). We use a method based on the f -sum rule to obtain the momentum -resolved experimental loss function and absorption spectra from EELS measurements. We characterize the main features in the direct and inverse dielectric functions of ZnO and their dispersion, associating them to single -particle features in the electronic band structure, while highlighting the important role of many -body effects such as plasmons and excitons. We discuss different signatures of the high anisotropy in the response function of ZnO, including the symmetry of the excitonic wave functions.