Functional metal-organic liquids

For decades, the study of coordination polymers (CPs) and metal-organic frameworks (MOFs) has been limited primarily to their behavior as crystalline solids. In recent years, there has been increasing evidence that they can undergo reversible crystal-to-liquid transitions. However, their "liquid" states have primarily been considered intermediate states, and their diverse properties and applications of the liquid itself have been overlooked. As we learn from organic polymers, ceramics, and metals, understanding the structures and properties of liquid states is essential for exploring new properties and functions that are not achievable in their crystalline state. This review presents state-of-the-art research on the liquid states of CPs and MOFs while discussing the fundamental concepts involved in controlling them. We consider the different types of crystal-to-liquid transitions found in CPs and MOFs while extending the interpretation toward other functional metal-organic liquids, such as metal-containing ionic liquids and porous liquids, and try to suggest the unique features of CP/MOF liquids. We highlight their potential applications and present an outlook for future opportunities. This review explores principles governing melting behaviors in coordination polymers and metal-organic frameworks, overviews their practical applications, and discusses design strategies for achieving liquid states in diverse metal-organic liquids.