Nickel-catalyzed C(sp2)-C(sp3) coupling via photoactive electron donor-acceptor complexes

被引:2
作者
Alsharif, Salman [1 ]
Zhu, Chen [1 ,3 ]
Liu, Xiushan [2 ]
Lee, Shao-Chi [1 ]
Yue, Huifeng [2 ]
Rueping, Magnus [1 ]
机构
[1] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr, KCC, KAUST, Thuwal 239556900, Saudi Arabia
[2] Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
[3] Eastern Inst Technol, Eastern Inst Adv Study, Ningbo 315200, Peoples R China
关键词
MECHANISMS; HALIDES;
D O I
10.1039/d4cc00217b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have developed a novel Ni-catalyzed reductive cross-coupling reaction of aryl bromides and alkyl iodides via a photoactive electron donor-acceptor (EDA) complex. This photo-induced process enables the efficient construction of C(sp(2))-C(sp(3)) bonds in the absence of an external photocatalyst. Electronically and structurally diverse aryl bromides, as well as secondary and primary alkyl iodides could undergo this transformation smoothly. Natural product derivatives were employed successfully, and UV-vis spectroscopy was utilized to gain mechanistic insight.
引用
收藏
页码:5153 / 5156
页数:4
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