Effect of screw speed in compounding of poly(butylene adipate-co-terephthalate)/thermoplastic starch blends and their processability by cast extrusion

被引:1
作者
Genovesi, Annalisa [1 ]
Gisario, Annamaria [2 ]
Barletta, Massimiliano [1 ]
机构
[1] Univ Roma Tre, Dipartimento Ingn Ind Elettron & Meccan, Via Vasca Navale 79, I-00146 Rome, Italy
[2] Sapienza Univ Roma, Dipartimento Ingn Meccan & Aerosp, Rome, Italy
关键词
cast extrusion; characterization; compounding; poly(butylene adipate-co-terephthalate) (PBAT); thermoplastic starch (TPS); THERMOPLASTIC STARCH; MICROCRYSTALLINE CELLULOSE; FUNCTIONAL-PROPERTIES; FILMS; NANOPARTICLES; CASSAVA;
D O I
10.1002/pol.20230901
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Blends of bio-polyesters cover a wide percentage of the market share and possess properties comparable to the ones of conventional polymers. Poly(butylene adipate-co-terephthalate) (PBAT) is a fossil-based compostable bioplastic, which possess good mechanical properties and processability. Blending PBAT with thermoplastic starch (TPS) allows to lower the cost of the final products and to increase the amount of bioderived material. The influence of the processing parameters on the morphology and on the mechanical properties of PBAT/TPS blends is studied. The compounds were produced via twin-screw extrusion and then films were produced via cast film extrusion. The quality of the dispersion is strongly related to the screw speed adopted during the compounding process. The quality of the film and their processability depend on the parameters adopted during the compounding process.
引用
收藏
页码:3334 / 3345
页数:12
相关论文
共 57 条
[11]   Enhanced properties of PBAT/TPS biopolymer blend with CuO nanoparticles for promising active packaging [J].
Bumbudsanpharoke, Nattinee ;
Harnkarnsujarit, Nathdanai ;
Chongcharoenyanon, Busarin ;
Kwon, Seongyoung ;
Ko, Seonghyuk .
FOOD PACKAGING AND SHELF LIFE, 2023, 37
[12]   Morphology and permeability of bio-based poly(butylene adipate-co-terephthalate) (PBAT), poly(butylene succinate) (PBS) and linear low-density polyethylene (LLDPE) blend films control shelf-life of packaged bread [J].
Bumbudsanpharoke, Nattinee ;
Wongphan, Phanwipa ;
Promhuad, Khwanchat ;
Leelaphiwat, Pattarin ;
Harnkarnsujarit, Nathdanai .
FOOD CONTROL, 2022, 132
[13]   Tear strength of ductile polyolefin films [J].
Chang, AC ;
Inge, T ;
Tau, L ;
Hiltner, A ;
Baer, E .
POLYMER ENGINEERING AND SCIENCE, 2002, 42 (11) :2202-2212
[14]   Robust multiphase and multilayer starch/polymer (TPS/PBAT) film with simultaneous oxygen/moisture barrier properties [J].
Chang, Christina C. ;
Trinh, Binh M. ;
Mekonnen, Tizazu H. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 593 :290-303
[15]   PBAT/TPS Composite Films Reinforced with Starch Nanoparticles Produced by Ultrasound [J].
Chaves da Silva, Normane Mirele ;
Cruz Correia, Paulo Romano ;
Druzian, Janice Izabel ;
Fakhouri, Farayde Matta ;
Lima Fialho, Rosana Lopes ;
Magalhaes Cabral de Albuquerque, Elaine Christine .
INTERNATIONAL JOURNAL OF POLYMER SCIENCE, 2017, 2017
[16]   Blends of PBAT with plasticized starch for packaging applications: Mechanical properties, rheological behaviour and biodegradability [J].
Dammak, Mohamed ;
Fourati, Yesmine ;
Tarres, Quim ;
Delgado-Aguilar, Marc ;
Mutje, Pere ;
Boufi, Sami .
INDUSTRIAL CROPS AND PRODUCTS, 2020, 144
[17]   Properties of Biodegradable Films Based on Poly(butylene Succinate) (PBS) and Poly(butylene Adipate-co-Terephthalate) (PBAT) Blends [J].
de Matos Costa, Anna Raffaela ;
Crocitti, Andrea ;
Hecker de Carvalho, Laura ;
Carroccio, Sabrina Carola ;
Cerruti, Pierfrancesco ;
Santagata, Gabriella .
POLYMERS, 2020, 12 (10) :1-17
[18]   An overview on properties and applications of poly(butylene adipate-co-terephthalate)-PBAT based composites [J].
Ferreira, Filipe V. ;
Cividanes, Luciana S. ;
Gouveia, Rubia F. ;
Lona, Liliane M. F. .
POLYMER ENGINEERING AND SCIENCE, 2019, 59 (s2) :E7-E15
[19]   Poly(lactic acid) formulations with improved toughness by physical blending with thermoplastic starch [J].
Ferri, J. M. ;
Garcia-Garcia, D. ;
Carbonell-Verdu, A. ;
Fenollar, O. ;
Balart, R. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2018, 135 (04)
[20]   Cellulose nanofibrils reinforced PBAT/TPS blends: Mechanical and rheological properties [J].
Fourati, Yesmine ;
Tarres, Quim ;
Delgado-Aguilar, Marc ;
Mutje, Pere ;
Boufi, Sami .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2021, 183 :267-275