Inherited construction of porous zinc hydroxide sulfate layer for stable dendrite-free Zn anode

A stable Zn anode for mitigating dendritic growth, corrosion, and byproducts is vital for exhibiting high-performance electrochemical properties in aqueous Zn-ion batteries. An artificial solid/electrolyte interphase is an effective protective strategy for Zn anodes. Herein, a uniform layer of zinc hydroxide sulfate (ZHS) derived in situ from a ZIF-8 membrane was developed on a Zn anode. The ZHS layer inherited a well-ordered structure and porous channels from the ZIF-8 membrane and exhibited high ionic conductivity, low electronic conductivity, and strong interactions with Zn2+ ions, which facilitated the regulation of homogeneous Zn2+ flux and deposition for dendritic inhibition. The strong interactions between H2O molecules and SO42- ions in the ZHS layer could alter the solvation structure of hydrated Zn2+ ions to facilitate the desolvation process, thus mitigating H2O-induced side reactions during Zn plating/stripping processes. The ZHS layer-coated Zn anode exhibited a remarkably long cycling lifespan of over 2800 h at a low current density of 1 mA cm-2 (1 mA h cm-2) and over 1100 h at a high current density of 10 mA cm-2 (5 mA h cm-2). This study provides a facile and feasible strategy to achieve the interfacial stability of Zn anodes for use in rechargeable aqueous Zn-ion batteries. A zinc hydroxide sulfate layer inheriting the ordered structure and porous channels of MOF was developed for high-performance Zn anodes.