Research progress on reaction process and catalysts for PBS precursor of 1,4-butanediol synthesis

被引：0

作者：

Li Q. ^{[1
]}

Wang C. ^{[1
]}

Xu S. ^{[1
]}

Zhang X. ^{[1
]}

Qiu M. ^{[1
]}

Liu M. ^{[1
]}

Cong M. ^{[1
]}

机构：

[1] CECEP Engineering Technology Research Institute, Beijing

来源：

Huagong Jinzhan/Chemical Industry and Engineering Progress | 2022年 / 41卷 / 11期

关键词：

1,4-butanediol; biocatalysis; biomass; catalyst; hydrogenation; polybutylene succinate;

D O I：

10.16085/j.issn.1000-6613.2022-0102

中图分类号：

学科分类号：

摘要：

As a fully biodegradable plastic, polybutylene succinate (PBS) is considered to be a potential degradable material to replace ordinary plastics. However, the cost of PBS is continuously rising because the price of its raw materials, especially 1, 4-butanediol (BDO), is going up. In order to thoroughly understand the process, current situation, existing problems and latest development of BDO synthesis, different fossil-based BDO synthesis routes were reviewed, and the progress of Cu-, Ni-, Pd-, Pt- and Rh-based catalysts used were described. Subsequently, the latest development of the BDO synthesis derived from biomass such as succinic acid, furfural/furan, 1, 4-anhydroerythritol and sugars were elaborated. Then the life cycle assessment, capital and operating costs of biomass derived BDO synthesis were briefly described. The comparison of BDO synthesis between bio- and fossil routes was given. Finally, the existing problems and development direction of BDO synthesis were outlined and expected. The key for synthesis BDO is to develop the low energy consumption and high efficiency catalysts for both the fossil- and bio-route in the future. © 2022 Chemical Industry Press. All rights reserved.

引用

页码：5771 / 5782

页数：11

共 71 条

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