Research progresses on supported precious metal catalysts for base-free aerobic oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid

被引：0
作者：
Yu X. [1 ]
Bao Q. [2 ]
Gao S. [3 ]
Zhang Y. [2 ]
机构：
[1] Division of Science and Technology, Jilin Institute Chemical Technology, Jilin
[2] School of Chemistry and Pharmaceutical Engineering, Jilin Institute Chemical Technology, Jilin
[3] Department of Chemical and Environmental Engineering, Yingkou Institute of Technology, Yingkou
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2021年 / 40卷 / 07期
关键词：
2; 5-furandicarboxylic acid; 5-hydroxymethylfurfural; Base-free; Catalysts; Oxidation;
D O I：
10.16085/j.issn.1000-6613.2020-1677
中图分类号：
学科分类号：
摘要：
The efficient and green catalytic conversion of 5-hydroxymethylfurfural (HMF) into higher value-added 2, 5-furandicarboxylic acid (FDCA) has become a research hotspot in the field of biomass energy conversion. The basic carrier supported precious metal catalysts for the base-free aerobic oxidation of HMF to FDCA have been extensively studied, and a series of results have been achieved. In this paper, the latest developments of hydrotalcite, hydroxyapatite, carbon materials, metal oxides and other carrier-supported noble metal catalysts for the base-free aerobic oxidation of HMF to FDCA are reviewed. The structure, properties, catalytic reaction parameters and catalytic activity for different catalysts are introduced. Moreover, the structure-activity relationship and the catalytic reaction mechanism are discussed. Finally, the future directions of the design and development of supported noble metal catalysts and mechanism exploration are pointed out for converting HMF to FDCA. © 2021, Chemical Industry Press Co., Ltd. All right reserved.
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页码：3760 / 3771
页数：11
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