Magnetic Solid-Phase Extraction with Dispersion of Magnetic Hypercrosslinked Polystyrene by Carbon Dioxide for the Extraction of Amphenicols from Honey and Milk in Their Determination by HPLC-MS/MS

被引：0
作者：
Goncharov, N. O. [1 ]
Tolmacheva, V. V. [1 ]
Lazarevich, T. V. [1 ,2 ]
Melekhin, A. O. [3 ]
Puryskin, I. D. [1 ]
Apyari, V. V. [1 ]
Dmitrienko, S. G. [1 ]
机构：
[1] Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia
[2] Univ Leipzig, D-04109 Leipzig, Germany
[3] Fed Ctr Anim Hlth, Vladimir 600901, Russia
来源：
JOURNAL OF ANALYTICAL CHEMISTRY | 2024年 / 79卷 / 09期
关键词：
amphenicols; honey; milk; magnetic solid-phase extraction; effervescent extraction; magnetic hypercrosslinked polystyrene; HPLC-MS/MS; POLYCYCLIC AROMATIC-HYDROCARBONS; EFFERVESCENT TABLETS; IONIC LIQUIDS; ORGANIC FRAMEWORKS; MICROEXTRACTION;
D O I：
10.1134/S1061934824700655
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A magnetic solid-phase extraction method with the dispersion of magnetic hypercrosslinked polystyrene (MHCPS) by carbon dioxide is proposed for the extraction and preconcentration of amphenicols (chloramphenicol, florfenicol, and thiamphenicol) from honey and milk before their determination by HPLC-MS/MS. Effervescent tablets, consisting of sodium bicarbonate, citric acid, and MHCPS in the case of honey and sodium bicarbonate and MHCPS in the case of milk, were used. The conditions for obtaining tablets were selected (the amount and ratio of the acid, base, and MHCPS in the composition of a tablet and its mass), ensuring the quantitative release of amphenicols. Procedures for the determination of amphenicols in honey and milk with the dispersion of the sorbent by carbon dioxide and the subsequent determination of the compounds by HPLC-MS/MS are developed. The limits of detection are 0.3-1 and 0.02-0.05 mu g/kg for honey and milk, respectively.
引用
收藏
页码：1296 / 1303
页数：8
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