Research progress of reverse water gas shift reaction

被引：0

作者：

Wang X. ^{[1
]}

Zhang W. ^{[1
]}

Yao Z. ^{[1
]}

Guo X. ^{[1
]}

Li C. ^{[1
]}

机构：

[1] State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Shanxi, Taiyuan

来源：

Huagong Jinzhan/Chemical Industry and Engineering Progress | 2023年 / 42卷 / 03期

关键词：

carbon dioxide; carbon monoxide; catalyst; reverse water gas shift reaction; thermodynamics;

D O I：

10.16085/j.issn.1000-6613.2022-0816

中图分类号：

学科分类号：

摘要：

Reverse water gas conversion (RWGS) reaction is a key step in the catalytic hydrogenation of carbon dioxide (CO2) to high value-added chemicals and fuels such as methanol, light olefins, aromatics and gasoline, which is of great significance for the utilization of CO2. This review summarizes the research progress of RWGS reaction in recent years, including thermodynamic analysis of RWGS reaction, catalytic mechanisms, selective catalysts and strategies to improve the performance of catalysts. From the perspective of thermodynamics, RWGS reaction is favorable at high temperature, as methanation reaction emerges at low temperature. The mechanisms of RWGS reaction mainly consist of redox mechanism and association mechanism, and the latter further contains a formate route and/or carboxylate route. Compared with other catalyst system, supported metal catalysts commonly exhibit a superior RWGS reaction performance. In addition, the rational design of RWGS reaction catalysts with high reactivity and durability could be realized by adding alkali metal additives, forming bimetallic alloy as well as modulating the metal-support interaction via selecting a good support or reducing the metal particle size. © 2023 Chemical Industry Press. All rights reserved.

引用

页码：1583 / 1594

页数：11

共 60 条

[1]

WANG W, WANG S P, MA X B, Et al., Recent advances in catalytic hydrogenation of carbon dioxide, Chemical Society Reviews, 40, 7, pp. 3703-3727, (2011)

[2]

ARESTA M, DIBENEDETTO A, ANGELINI A., Catalysis for the valorization of exhaust carbon: From CO2 to chemicals, materials, and fuels. Technological use of CO2, Chemical Reviews, 114, 3, pp. 1709-1742, (2014)

[3]

POROSOFF M D, YAN B H, CHEN J G G., Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: Challenges and opportunities, Energy & Environmental Science, 9, 1, pp. 62-73, (2016)

[4]

LEUNG D Y C, CARAMANNA G, MAROTO-VALER M M., An overview of current status of carbon dioxide capture and storage technologies, Renewable and Sustainable Energy Reviews, 39, pp. 426-443, (2014)

[5]

FAZLOLLAHI F, BOWN A, SAEIDI S, Et al., Transient natural gas liquefaction process comparison-dynamic heat exchanger under transient changes in flow, Applied Thermal Engineering, 109, pp. 775-788, (2016)

[6]

OUYANG B, TAN W L, LIU B., Morphology effect of nanostructure ceria on the Cu/CeO2 catalysts for synthesis of methanol from CO2 hydrogenation, Catalysis Communications, 95, pp. 36-39, (2017)

[7]

BAHRI S, VENEZIA A M, UPADHYAYULA S., Utilization of greenhouse gas carbon dioxide for cleaner Fischer-Tropsch diesel production, Journal of Cleaner Production, 228, pp. 1013-1024, (2019)

[8]

POROSOFF M D, YANG X F, BOSCOBOINIK J A, Et al., Molybdenum carbide as alternative catalysts to precious metals for highly selective reduction of CO2 to CO, Angewandte Chemie International Edition, 53, 26, pp. 6705-6709, (2014)

[9]

YUAN F, ZHANG G H, ZHU J, Et al., Boosting light olefin selectivity in CO2 hydrogenation by adding Co to Fe catalysts within close proximity, Catalysis Today, 371, pp. 142-149, (2021)

[10]

YANG S, LI M Z, NAWAZ M A, Et al., High selectivity to aromatics by a Mg and Na co-modified catalyst in direct conversion of syngas, ACS Omega, 5, 20, pp. 11701-11709, (2020)

← 1 2 3 4 5 6 →