Synthesis and characterization of new nanocomposite PW 11 Mn@CuO@PAN as an efficient nanocatalyst for deep oxidative desulfurization of real/model fuels

被引:9
作者
Rezvani, Mohammad Ali [1 ]
Bakhtiyari, Ali [1 ]
Rahmani, Parvin [1 ]
机构
[1] Univ Zanjan, Fac Sci, Dept Chem, Zanjan 451561319, Iran
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2024年 / 303卷
关键词
Phosphotungstate; Copper oxide; Polyaniline; Catalytic oxidation desulfurization; Heterogeneous nanocatalyst; Thiophene; HIGH-PERFORMANCE NANOCATALYST; HETEROGENEOUS CATALYST; ELECTRICAL-PROPERTIES; GRAPHENE OXIDE; KEGGIN-TYPE; GAS OIL; GASOLINE; POLYANILINE; BIODESULFURIZATION; COMPOSITE;
D O I
10.1016/j.mseb.2024.117314
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To obtain clean fuel, a new nanocatalyst was synthesized utilizing K 4 PW 11 MnO 39 (PW 11 Mn), copper oxide (CuO), and polyaniline (PAN) to applied as a uniform nanocatalyst for catalytic oxidation desulfurization (Cat-ODS) reactions. The as -prepared nanocomposite was formulated using various characterization techniques such as FTIR, UV - vis, XRD, SEM, and EDX methods. Experiments pertaining of the elimination of sulfur -containing compounds present in real/model fuel were conducted through the implementation of Cat-ODS methodology. In contrast to the catalytic effectiveness displayed by the bulk substances, PW 11 Mn@CuO@PAN demonstrated a significantly enhanced performance in the Cat-ODS system. In accordance with the findings of the experiment, the inquiries conducted regarding the Cat-ODS of gasoline disclosed that the level of sulfur was diminished from 0.4997 to 0.0117 wt% with 98 % efficiency in 1 h contracting time at temperature of 35 degrees C. The PW 11 Mn@CuO@PAN can be repeatedly recycled for 5 times without experiencing a significant decrease in its activity.
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页数:12
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