One-step direct construction of S-scheme BaTi2O5/g-C3N4 heterojunction for enhanced photocatalytic hydrogen evolution

Heterojunction photocatalysis has been widely studied as a means of efficiently converting solar energy to chemicals. However, the major challenge in developing high-performing heterojunction photocatalytic systems lies in achieving efficient transfer of electrons between the components. Herein, a novel S-scheme heterojunction photocatalyst was developed by combining BaTi(2)O5 nanorods with g-C3N4 lamellae. The preferential deposition of Pt nanoparticles as cocatalyst via the one-step impregnation-reduction method on g-C3N4 nanosheets with enhanced interfacial contact and strong electronic interaction has been proved essential for the photocatalytic performance. The developed Pti(mp)/20BaTi(2)O(5)/g-C3N4 photocatalyst delivers the optimal hydrogen production rate of 2587 mu mol g(-1) h(-1) with high stability after cycles. Photoelectrochemical analysis and theoretical calculation suggest that the formation of BaTi2O5/g-C3N4 heterojunction results in the staggered band alignment and improved charge carrier dynamics. This work highlights the importance and feasibility of promoting photocatalysis by a new S-scheme heterojunction with viable cocatalysts.