Assessing the effect of K2CO3 and aqueous phase recycling on hydrothermal liquefaction of corn stover

被引：11

作者：

Carpio, Rowena B. ^{[1
]}

Avendano, Chris Ian L.

Basbas, Carlo A. ^{[1
]}

Habulan, Aljay A. ^{[1
]}

Guerrero, Gino Apollo M. ^{[1
]}

Maguyon-Detras, Monet Concepcion ^{[1
]}

Bambase Jr, Manolito E. ^{[1
]}

机构：

[1] Univ Philippines Los Banos, Dept Chem Engn, Los Banos 4031, Laguna, Philippines

来源：

BIORESOURCE TECHNOLOGY REPORTS | 2022年 / 18卷

关键词：

Hydrothermal liquefaction; Lignocellulose; Corn stover; Alkali catalyst; Aqueous phase recycling; BIO-OIL; BIOMASS; TEMPERATURE; CELLULOSE; PRODUCTS; ALKALI; YIELD; WATER;

D O I：

10.1016/j.biteb.2022.101093

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The effects of reaction temperature (300-340 degrees C) and reaction time (30-90 min), catalyst loading (0-10% K2CO3), and aqueous phase recycling (up to 3 recycling rounds) on the hydrothermal liquefaction (HTL) of corn stover were investigated. The oil yield ranged from 0.28 to 14.54%daf. A high reaction temperature and a long reaction time have a synergistic effect on the oil production under non-catalytic HTL. The effect of K2CO3 loading on oil yield is dependent on the reaction temperature. The FTIR analysis of the solid residue showed that the peak characteristics of lignin and cellulose are still intact without or with different K2CO3 loading suggesting low lignin and cellulose degradation. The effect of the aqueous phase with the presence of K2CO3 showed an increased oil yield, energy recovery, and abundance in silanes and siloxanes after the 3rd round of recycling.

引用

页数：8

共 43 条

[1] Abel E.W., 1995, 4-Silicones, P111, DOI [10.1016/B978-008046519-7.00016-2, DOI 10.1016/B978-008046519-7.00016-2]
[2] Agilent Technologies I., 2016, The Essential Chromatography & Spectroscopy Catalog, GC and GC/MS 2015-2016 Edition-Columns
[3] Liquefaction of empty palm fruit bunch (EPFB) in alkaline hot compressed water
Akhtar, Javaid
Kuang, Soo Kim
Amin, NorAishah Saidina
[J]. RENEWABLE ENERGY, 2010, 35 (06) : 1220 - 1227
[4] Analysis of damage caused by siloxanes in stationary reciprocating internal combustion engines operating with landfill gas
Alvarez-Florez, Jesus
Egusquiza, Eduard
[J]. ENGINEERING FAILURE ANALYSIS, 2015, 50 : 29 - 38
[5] Effect of hydrothermal liquefaction aqueous phase recycling on bio-crude yields and composition
Biller, Patrick
Madsen, Rene B.
Klemmer, Maika
Becker, Jacob
Iversen, Bo B.
Glasius, Marianne
[J]. BIORESOURCE TECHNOLOGY, 2016, 220 : 190 - 199
[6] HYDROTHERMAL DEGRADATION OF POLYMERS DERIVED FROM PLANTS
BOBLETER, O
[J]. PROGRESS IN POLYMER SCIENCE, 1994, 19 (05) : 797 - 841
[7] Carpio R B., 2021, Bioresource Technology Reports, V14, P100679, DOI DOI 10.1016/J.BITEB.2021.100679
[8] Carpioa Rowena, 2018, International Journal of Smart Grid and Clean Energy, V7, P17, DOI 10.12720/sgce.7.1.13-23
[9] Crocker, 2008, DETERMINATION STRUCT, V1617, P1
[10] Liquefaction of biomass using glycerol
Demirbas, A.
[J]. ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2008, 30 (12) : 1120 - 1126

← 1 2 3 4 5 →