Synthesis of Benzimidazole and Benzothiazole Derivatives using Reusable Waste Stem of Trigonella Foenum-graecum Assisted Zinc Sulphide Nanoparticles: A Green and Efficient Solid Acid Catalyst

被引:0
作者
Valvi A.K. [1 ]
Gavit H.J. [1 ]
Nayak S.S. [2 ]
Shivankar V.S. [3 ]
Wadhawa G.C. [2 ]
机构
[1] Annasaheb Awate Arts, Commerce and Hutatma Babu Genu Science College, Manchar, Maharashtra, Pune
[2] Rayat Shikshan Sanstha's Karmaveer Bhaurao Patil College, Vashi, Navi Mumbai
[3] Rayat Shikshan Sanstha's Chhatrapati Shivaji College, Maharashtra, Satara
关键词
Benzimidazole; Benzothiazole; Condensation reaction; Nanoparticles; Plant extract;
D O I
10.1016/j.matpr.2022.10.023
中图分类号
学科分类号
摘要
In this study, the simple and rapid methods for the preparation of benzimidazole and benzothiazole by the condensation of o-phenylenediamine with the aromatic aldehyde in presence of the zinc sulphide nanoparticles derived from the waste stem of the Trigonella foenum-graecum. The catalyst was prepared by using the waste stem of the Trigonella foenum-graecum. Most of the reaction carried under the mild condition with very high excellent yield. The method is used for the aromatic, unsaturated and heteroaromatic aldehyde. The main advantage of this method is that it takes very short reaction time, solvent free reaction condition, reusable catalyst, milder reaction, easy workup and waste stem of the plant was used. © 2022 Elsevier Ltd
引用
收藏
页码:481 / 486
页数:5
相关论文
共 64 条
[31]  
Hegedus A., Hell Z., Potor A., Zeolite-catalyzed environmentally friendly synthesis of benzimidazole derivatives, Synth. Commun., 36, pp. 3625-3630, (2006)
[32]  
Mobinikhaledi A., Forughifar N., Zendehdel M., Jabbarpour M., Conversion of aldehydes to benzimidazoles using NaY zeolite, Synth. React. Inorg. Met. Org. Nano-Met. Chem., 38, pp. 390-393, (2008)
[33]  
Mobinikhaledi A., Zendehdel M., Goudarzi F., Bardajee G.R., Nano-Ni(II)/Y Zeolite catalyzed synthesis of 2-aryl- and 2-alkyl benzimidazoles under solvent-free conditions, Synth. React. Inorg. Met. Org. Nano-Met. Chem., 46, pp. 1526-1531, (2016)
[34]  
Bahrami K., Khodaei M.M., Nejati A., Synthesis of 1,2-disubstituted benzimidazoles, 2-substituted benzimidazoles and 2-substituted benzothiazoles in SDS micelles, Green Chem., 12, pp. 1237-1241, (2010)
[35]  
Nguyen T.T., Nguyen X.-T.-T., Nguyen T.-L.-H., Tran P.H., Synthesis of benzoxazoles, benzimidazoles, and benzothiazoles using a Brønsted acidic ionic liquid gel as an efficient heterogeneous catalyst under asolvent-free condition, ACS Omega, 4, pp. 368-373, (2019)
[36]  
Adharvana Chari M., Shobha D., Sasaki T., Room temperature synthesis of benzimidazole derivatives using reusable cobalt hydroxide (II) and cobalt oxide (II) as efficient solid catalysts, Tetrahedron Lett., 52, pp. 5575-5580, (2011)
[37]  
Das B., Kanth B.S., Reddy K.R., Kumar A.S., Sulfonic acid functionalized silica as an efficient heterogeneous recyclable catalyst for one-pot synthesis of 2-substituted benzimidazoles, J. Heterocycl. Chem., 45, pp. 1499-1502, (2008)
[38]  
Bahrami K., Bakhtiarian M., Mesoporous titania-alumina mixed oxide: A heterogeneous nanocatalyst forthe synthesis of 2-substituted benzimidazoles, benzothiazoles and benzoxazoles, ChemistrySelect, 3, pp. 10875-10880, (2018)
[39]  
Chen B., Zhang C., Niu L., Shi X., Zhang H., Lan X., Bai G., Biomass-derived N-doped carbonmaterials with silica-supported ultrasmall ZnO nanoparticles: robust catalysts for the Green synthesis ofbenzimidazoles, Chem. Eur. J., 24, pp. 3481-3487, (2018)
[40]  
Bandyopadhyay P., Sathe M., Ponmariappan S., Sharma A., Sharma P., Srivastava A.K., Kaushik M.P., Exploration of in vitro time point quantitative evaluation of newly synthesized benzimidazole andbenzothiazole derivatives as potential antibacterial agents, Bioorg. Med. Chem. Lett., 21, pp. 7306-7309, (2011)