In-Situ-Generated Fluoride-Assisted Rapid Dissolution of Uranium Oxides by Ionic Liquids

被引：6

作者：

Goyal, Priya ^{[1
]}

Sengupta, Arijit ^{[1
,4
]}

Srivastava, Ashutosh ^{[1
]}

Mukherjee, Sumanta ^{[2
]}

Rout, Vaibhavi V. ^{[3
]}

Mohapatra, Prasanta K. ^{[1
,4
]}

机构：

[1] Bhabha Atom Res Ctr, Radiochem Div, Mumbai 400085, India

[2] Bhabha Atom Res Ctr, Prod Dev Div, Mumbai 400085, India

[3] Bhabha Atom Res Ctr, Radioanalyt Chem Div, Mumbai 400085, India

[4] Homi Bhabha Natl Inst, Mumbai 400094, India

来源：

INORGANIC CHEMISTRY | 2024年 / 63卷 / 16期

关键词：

ELECTROCHEMICAL-BEHAVIOR; DIRECT ELECTRODEPOSITION; EXTRACTION; URANYL; SPECIATION; KINETICS; COMPLEXATION; ADSORPTION; STABILITY; MECHANISM;

D O I：

10.1021/acs.inorgchem.3c04075

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A quantitative, rapid, endothermic dissolution of U3O8 in C(4)mim<middle dot>PF6 (1-alkyl-3-methyl imidazolium hexafluorophosphate) has been achieved within 2 h at 65 degrees C by in situ generated fluoride ions by pre-equilibrating the ionic liquid with suitable concentrations of nitric acid. The efficiency of the dissolution followed the trend: UO3 > UO2 > U3O8. The fluoride generation was found to increase with the concentration of nitric acid being equilibrated, the water content of the ionic liquid, and also the time of equilibration. The rate of dissolution of U3O8 followed the trend: C(4)mim<middle dot>PF6> C(6)mim<middle dot>PF6 > C(8)mim<middle dot>PF6. The maximum loading observed for the present case was 200 mg mL(-1) which is considered to be quite high with an ionic liquid. The effects of different acid pre-equilibration (HClO4, HCl) on F- generation and subsequent dissolution characteristics have also been investigated. The in situ F- generation, as well as U(3)O8 dissolution, were found to predominantly follow a pseudo-second-order rate kinetics, while the rate constants for U3O8 dissolution were found to be higher than that of F- generation. The dissolved uranium was successfully electrodeposited on a Cu plate, as confirmed by EDXRF, while the formation of UO2 was revealed from the XRD pattern of the deposit.

引用

页码：7161 / 7176

页数：16

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