Microwave-assisted reduction and sintering to construct hybrid networks of reduced graphene oxide and MXene for electromagnetic interference shielding

被引:19
作者
Cai W. [1 ]
Ma W. [2 ]
Chen W. [3 ]
Liu P. [3 ]
Liu Y. [4 ]
Liu Z. [5 ]
He W. [6 ]
Li J. [6 ]
机构
[1] School of Chemical Engineering, Sichuan University, Chengdu
[2] State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu
[3] College of Materials Science & Engineering, Huaqiao University, Xiamen
[4] Technology Innovation Center for Exploitation of Marine Biological Resources, Third Institute of Oceanography, Ministry of Natural Resources, Xiamen
[5] College of Materials Science and Engineering, Shenzhen University, Shenzhen
[6] China Tobacco Fujian Industrial CO., LTD, Xiamen
基金
中国国家自然科学基金;
关键词
Hybrid; Polymer-matrix composites (PMCs); Sintering; Surface treatments;
D O I
10.1016/j.compositesa.2022.106928
中图分类号
学科分类号
摘要
Graphene is a prospective electromagnetic interference (EMI) shielding material in light of remarkable electrical conductivity. Nevertheless, the preparation of graphene through reduction of graphene oxide (GO) is an energy/time consuming process. We utilized Ti3C2Tx as an efficient initiator to achieve the thermal reduction of GO under microwave irradiation. Simultaneously, the continuous networks of rGO/Ti3C2Tx were constructed in sintered composite by locally melting and welding polysulfone under appropriate irradiation conditions. The composite with a 1:4 ratio of GO to Ti3C2Tx treated by irradiation of 10 s possessed an EMI SE of 52.81 dB with a thickness of 2 mm, while the shielding effectiveness of reflection (SER) only reached 4.8 dB. Besides, the intensity ratio of D to G-band (ID/IG) for composite treated by appropriate microwave dropped from 1.20 to 0.74. Therefore, selective microwave heating might be a clean and low-consumption strategy for large-scale production of rGO and manufacture of high-performance composites with EMI shielding property. © 2022 Elsevier Ltd
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