Effect of the Conditions of the Preparation of the Impregnating Solution and Heat Treatment on the Activity of Hydrotreating Catalysts

被引:0
作者
Arkhipova, I. A. [1 ]
Petrova, E. G. [1 ]
Leontyev, A. V. [1 ]
Fadeev, V. V. [1 ]
Zaglyadova, S. V. [1 ]
Kuptsov, A. Kh. [1 ]
机构
[1] United Res & Dev Ctr LLC, Brentwood, NH 03833 USA
关键词
hydrotreating catalyst; impregnating solution; cobalt carbonate; calcination; polyanions; Raman spectroscopy; desulfurization;
D O I
10.1007/s10553-024-01677-y
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A study was carried out on the quality of the cobalt carbonate raw material and heat treatment conditions on the activity of Co-Mo and Ni-Mo hydrotreating catalysts for a mixed diesel fraction. The relevant properties of the impregnation solution are the purity of the cobalt carbonate starting material and the synthesis temperature. A Raman spectroscopic method was proposed for monitoring the cobalt carbonate quality. Heat treatment of the catalyst was found to affect its activity. The optimal ultimate calcination temperatures for the Co-Mo and Ni-Mo catalysts were found to be very different.
引用
收藏
页码:250 / 257
页数:8
相关论文
共 16 条
[1]  
[Anonymous], USA Patent, Patent No. [4,409,131, 4409131]
[2]  
[Anonymous], USA Patent, Patent No. [3,232,887, 3232887]
[3]  
[Anonymous], Russian Patent, Patent No. [2,573,561, 2573561]
[4]  
[Anonymous], USA Patent, Patent No. [4,818,743, 4818743]
[5]  
[Anonymous], USA Patent, Patent No. [10,537,883, 10537883]
[6]  
[Anonymous], USA Patent, Patent No. [3,840,472, 3840472]
[7]   Spatially resolved Raman and UV-visible-NIR spectroscopy on the preparation of supported catalyst bodies:: Controlling the formation of H2PMo11CoO405- inside Al2O3 pellets during impregnation [J].
Bergwerff, JA ;
van de Water, LGA ;
Visser, T ;
de Peinder, P ;
Leliveld, BRG ;
de Jong, KP ;
Weckhuysen, BM .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (16) :4592-4601
[8]   Stability of the phospho-molybdic Dawson-type ion P2Mo18O626- in aqueous media [J].
Briand, LE ;
Valle, GM ;
Thomas, HJ .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (02) :299-304
[9]   Anderson type heteropolyoxomolybdates in catalysis:: 1.: (NH4)3[CoMo6O24H6]•7H2O/γ-Al2O3 as alternative of Co-Mo/γ-Al2O3 hydrotreating catalysts [J].
Cabello, CI ;
Botto, IL ;
Thomas, HJ .
APPLIED CATALYSIS A-GENERAL, 2000, 197 (01) :79-86
[10]   Monitoring hydrotreating catalysts synthesis and deactivation using Raman spectrometry [J].
Digne, M. ;
Marchand, K. ;
Bourges, P. .
OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES, 2007, 62 (01) :91-99