Cationization of Cellulose Dissolved in TEAOH/urea Solvent and its Preparation of Cellulose Beads: Effect of Added Amount of GTAC

被引:0
作者
Kim Y. [1 ]
Jang M. [1 ]
Cho B.-U. [2 ]
机构
[1] Department of Paper Science & Engineering, College of Forest and Environmental Science, Kangwon National University
[2] Program of Paper Material Science & Engineering, College of Forest and Environmental Science, Kangwon National University
来源
Palpu Chongi Gisul/Journal of Korea Technical Association of the Pulp and Paper Industry | 2022年 / 54卷 / 06期
关键词
Cellulose beads; chemical modification; GTAC; particle size; surface tension; zeta potential;
D O I
10.7584/JKTAPPI.2022.12.54.6.85
中图分类号
学科分类号
摘要
To widen the applications, cationic cellulose beads were synthesized by adding glycidyltrimethylammonium chloride (GTAC) to cellulose fibers dissolved in a mixture of tetraethylammonium hydroxide and urea at room temperature for cationic modification, and dropping the cationic cellulose solution into an acetic acid solution. Herein, the effects of the added GTAC amount on the properties of cationic cellulose soultion and cellulose beads were investigated. It was observed that increasing the amount of GTAC increased the viscosity and surface tension of the cationically modified cellulose solution and increased the particle size of the cellulose beads. Furthermore, the zeta potential of the cellulose beads can be controlled by modifying the GTAC amount. © 2022 Korean Technical Assoc. of the Pulp and Paper Industry. All rights reserved.
引用
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页码:85 / 93
页数:8
相关论文
共 28 条
[1]  
Moon S.M., Jeon S.H., Eom T, Shim B.S., Recent research trends in eco-friendly materials for solving environmental micro-plastic problems, Prospectives of Industrial Chemistry, 22, 2, pp. 25-43, (2019)
[2]  
Choi J.Y., A study on biopolymer as a future fiber material, Journal of the Korean Society Design Culture, 18, 1, pp. 481-493, (2012)
[3]  
Klemm D., Heublein B., Fink H.-P., Bohn A., Cellulose: Fascinating biopolymer and sustainable raw material, Angewandte Chemie Int. Ed, 44, pp. 3358-3393, (2005)
[4]  
Sood Y.V., Tyagi R., Tyagi S., Pande P.C., Tondon R., Surface charge of different paper making raw materials and its influence on paper properties, J. Scientific & Industrial Research, 69, pp. 300-304, (2010)
[5]  
Sim K.J., Youn H.J., Ahn J.G., Lee J.G., Lee H.Y., Jo Y.H., Surface modification of nanofibrillated cellulose by LbL (Layer-by-Layer) multilayering and its effect on the dewatering ability of suspension, Journal of Korea TAPPI, 46, 1, pp. 46-55, (2014)
[6]  
Lee J.Y., Park T.U., Jo H.M., Kim K.M., Kim C.H., Study on surface modification of cellulose nanofibril with cationic polyelectrolyte, Journal of Korea TAPPI, 50, 4, pp. 116-122, (2018)
[7]  
Lee J.Y., Kim S.H., Kim K.M., Sung Y. J., Study on the surface modification of pulp with cationic polyelectrolyte for the manufacture of cationic cellulose nanofibril, Journal of Korea TAPPI, 51, 6, pp. 152-157, (2019)
[8]  
Hasani M., Cranston E.D., Westman G., Gray D., Cationic surface functionalization of cellulose nanocrystals, Soft Matter, 4, pp. 2238-2244, (2008)
[9]  
Kim K.M., Lee J.Y., Kim C.H., Park T.U., Jo H. M., Effect of the wet-end addition of cationic cellulose nanofibril on paper strength, Journal of Korea TAPPI, 50, 2, pp. 29-35, (2018)
[10]  
Li P., Sirviӧ J.A., Asante B., Liimatainen H., Recyclable deep eutectic solvent for the production of cationic nanocelluloses, Carbohydrate Polymers, 199, pp. 219-227, (2018)