Solid polymer electrolyte blends with varied compositions of poly(ethylene oxide) (PEO)/carboxymethyl cellulose (Na-CMC) in 10/90, 50/50, and 90/10 compositions have been successfully prepared by means of the solution cast technique at room temperature. The modification of the structural, optical, and electrical properties of the prepared blend samples was studied by employing XRD, FTIR, UV-Vis, and electrical impedance spectroscopy methods. X-ray diffraction studies revealed that the crystalline nature gradually transforms into amorphous as the Na-CMC content increases in the sample. The variation of bands noticed in the Fourier transform infrared spectroscope characteristic spectrum of the blends reveals the formation of complexes between the individual polymers. The analysis of optical properties using a UV-Vis spectrometer in the wavelength range of 900-1100nm, shows a gradual decrease in the optical indirect energy band gap with an increase in Na-CMC content in the blend. The study of the electrical properties of the blend carried out in the frequency range 50 Hz-1MHz and temperature range 303K-338K, using an electrical impedance analyzer reveals that, the dielectric constant and loss decrease with the rise in frequency, exhibiting the usual behavior of the polymers. AC conductivity is found to increase with an increase in temperature. The highest value of ionic conductivity is found to be 6.06 x 10-3Scm-1 for the blend with a 10/90 composition.
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King Abdulaziz Univ, Fac Sci, Dept Phys, Al Faisaliah Campus, Jeddah, Saudi Arabia
Univ Jeddah, Coll Sci, Dept Phys, Jeddah, Saudi ArabiaKing Abdulaziz Univ, Fac Sci, Dept Phys, Al Faisaliah Campus, Jeddah, Saudi Arabia
Abutalib, M. M.
;
Rajeh, A.
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Amran Univ, Fac Sci, Phys Dept, Amran, YemenKing Abdulaziz Univ, Fac Sci, Dept Phys, Al Faisaliah Campus, Jeddah, Saudi Arabia
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Taif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Taif Univ, Univ Coll Turabah, Dept Phys, POB 11099, At Taif 21944, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Badawi, Ali
;
Alharthi, Sami S.
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Taif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Alharthi, Sami S.
;
Alotaibi, Abdullah A.
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Shaqra Univ, Dept Chem, Coll Sci & Humanities, POB 11911, Ad Dawadmi, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Alotaibi, Abdullah A.
;
Althobaiti, M. G.
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Taif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
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Housing & Bldg Natl Res Ctr HBRC, Bldg Phys & Environm Inst, Giza 12311, EgyptAin Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, Egypt
El-Khodary, Sherif
;
Elhaes, Hanan
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Ain Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, EgyptAin Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, Egypt
Elhaes, Hanan
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Nada, Nadra
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Ibrahim, Medhat
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Natl Res Ctr, Spect Dept, Mol Spect & Modeling Unit, 33 El Bohouth St, Giza 12622, EgyptAin Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, Egypt
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King Abdulaziz Univ, Fac Sci, Dept Phys, Al Faisaliah Campus, Jeddah, Saudi Arabia
Univ Jeddah, Coll Sci, Dept Phys, Jeddah, Saudi ArabiaKing Abdulaziz Univ, Fac Sci, Dept Phys, Al Faisaliah Campus, Jeddah, Saudi Arabia
Abutalib, M. M.
;
Rajeh, A.
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Amran Univ, Fac Sci, Phys Dept, Amran, YemenKing Abdulaziz Univ, Fac Sci, Dept Phys, Al Faisaliah Campus, Jeddah, Saudi Arabia
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Taif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Taif Univ, Univ Coll Turabah, Dept Phys, POB 11099, At Taif 21944, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Badawi, Ali
;
Alharthi, Sami S.
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Taif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Alharthi, Sami S.
;
Alotaibi, Abdullah A.
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Shaqra Univ, Dept Chem, Coll Sci & Humanities, POB 11911, Ad Dawadmi, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
Alotaibi, Abdullah A.
;
Althobaiti, M. G.
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Taif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi ArabiaTaif Univ, Dept Phys, Coll Sci, POB 11099, At Taif 21944, Saudi Arabia
机构:
Housing & Bldg Natl Res Ctr HBRC, Bldg Phys & Environm Inst, Giza 12311, EgyptAin Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, Egypt
El-Khodary, Sherif
;
Elhaes, Hanan
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Ain Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, EgyptAin Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, Egypt
Elhaes, Hanan
;
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Nada, Nadra
;
Ibrahim, Medhat
论文数: 0引用数: 0
h-index: 0
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Natl Res Ctr, Spect Dept, Mol Spect & Modeling Unit, 33 El Bohouth St, Giza 12622, EgyptAin Shams Univ, Fac Women Arts Sci & Educ, Phys Dept, Cairo 11757, Egypt