Mechanical and thermal properties of pulp fiber/polylactic acid composite

被引:0
|
作者
She Y. [1 ]
Fu Y. [2 ]
Zhu Q. [1 ]
Wu S. [3 ]
Xu X. [1 ]
机构
[1] College of Materials Science and Engineering, Nanjing Forestry University, Nanjing
[2] State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai
[3] College of Furnishings Design and Industry Design, Nanjing Forestry University, Nanjing
来源
Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2022年 / 39卷 / 10期
关键词
Biocomposite; Bleached pulp fiber; Internal mixing; Polylactic acid (PLA); Two-screw extrusion;
D O I
10.13801/j.cnki.fhclxb.20211115.005
中图分类号
学科分类号
摘要
Biomass-derived fillers reinforced composites have always been considered as potential substitutes for petroleum-based products. In this work, high content of bleached pulp fibers (10wt% to 50wt%) were adopted to modify polylactic acid (PLA) with maleic anhydride grafted polypropylene (MA-g-PP) as the compatibilizer. Two pre-melting processes of fiber/PLA composites were tried, i.e., roll-grinding plus extruding as well as internal mixing process. Tensile test, SEM, FTIR、DMA and TGA were employed to comprehensively investigate the effects of processing methods and fiber content on the mechanical and thermal properties, and microstructure of fiber/PLA composites. The results showed that, internal mixing process (IM process) is more effective than grinding and extruding process (GE process) to achieve good dispersion and almost oriented-arrangement of the fibers in the matrix. IM-processed composites with fiber content up to 50wt% acquired the maximum tensile strength (50.49 MPa, slightly higher than PLA) and Young's modulus (2.56 GPa, 45.8% higher than PLA). Damping capacity and loss factor of composites are reduced by the rigid filled pulp fibers, while the peak temperature is positively migrated. Pulp fibers added have no adversely effect on thermal stability and improve the residues content of PLA composites. It can be concluded that bleached pulp fiber is an effective filler for PLA-based composites. © 2022, Editorial Office of Acta Materiae Compositae Sinica. All right reserved.
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页码:4856 / 4867
页数:11
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