Monomeric and Polymeric Cyclopentadienyl Dysprosium Complexes Based on the Acenaphthene-1,2-diimine Ligand

被引：0
作者：
Lukina, D. A. [1 ]
Skatova, A. A. [1 ]
Kozlova, E. A. [1 ]
Fedushkin, I. L. [1 ]
机构：
[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
dysprosium; cyclopentadienyl; 1,2-bis(arylimino)acenaphthene; coordination polymer; redox-active ligand; METAL-ORGANIC FRAMEWORKS; EUROPIUM COMPLEXES; CRYSTAL-STRUCTURES; REDOX ISOMERISM; LANTHANIDES; REDUCTION;
D O I：
10.1134/S1070328424600207
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [(Dpp-bian)DyI(Dme)(2)] (Dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene, Dme is CH3OCH2CH2OCH3) with Cp*K (Cp* is C5Me5) in toluene followed by crystallization from benzene affords crystals of the 1D coordination polymer [(Dpp-bian)DyIKCp*](n) (I)center dot 2.6C(6)H(6) (26%) and crystals of the monomeric complex [(Dpp-bian)DyCp*(Dme)] (II)center dot 1.5C(6)H(6) (12%). The same reaction in 1,2-dimethoxyethane followed by crystallization from benzene makes it possible to isolate only complex II center dot 1.5C(6)H(6) in a yield of 48%. The synthesized compounds are characterized by IR and UV spectroscopy and elemental and thermogravimetric analyses. Their molecular structures are determined by XRD (CIF files CCDC nos. 2298407 (I) and 2298408 (II)).
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页码：307 / 315
页数：9
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